CFC-Free Aqueous Fire Extinguishing Agent for Hydrophobic Surfaces

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Solution Overview

Problem

Current fire extinguishing agents, including water, face challenges such as low wettability and permeability, leading to insufficient cooling and delayed firefighting, with environmental and health concerns exacerbated by the increasing frequency of fires and decreasing water resources.

Innovation Solution

A CFC-free and phosphorus-free aqueous fire extinguishing agent comprising sulfosuccinic acid ester and a wetting agent, which enhances the wettability and permeability of water, allowing for rapid temperature reduction and improved firefighting efficiency while being non-toxic and biodegradable.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If water is used as a fire extinguishing agent, then environmental friendliness and cost-effectiveness are improved, but wettability and permeability are insufficient due to high surface tension

Engineering Contradiction:
Improveenvironmental friendlinessVSAvoidwettability
Core Design Contradiction:
Object-affected harmful factorsVSEase of operation

Solution Approach 1:

The patent introduces surfactants as intermediary substances that mediate between water and hydrophobic burning substances. The surfactant molecules reduce water's surface tension and enable water to wet and penetrate hydrophobic surfaces, thereby resolving the contradiction between using environmentally friendly water and achieving effective wettability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the physical-chemical parameters of water by adding surfactants, which alter water's surface tension and wettability characteristics. This parameter change enables water to effectively contact and penetrate hydrophobic burning substances while maintaining its environmental friendliness.

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If water is used as a fire extinguishing agent, then cost-effectiveness is improved, but cooling function is insufficient due to low permeability

Engineering Contradiction:
Improvecost-effectivenessVSAvoidcooling function
Core Design Contradiction:
Object-affected harmful factorsVSTemperature

Solution Approach 1:

The surfactant acts as an intermediary that enables water to penetrate into the interior of burning substances. By improving permeability, the surfactant allows water to reach deeper regions of the burning material, enhancing the cooling function while maintaining cost-effectiveness.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes water's permeability parameter through surfactant addition, enabling water to penetrate hydrophobic burning substances more effectively. This enhanced permeability improves the cooling function by allowing water to reach and cool the interior regions of burning materials.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If conventional fire extinguishing agents are used, then firefighting effectiveness is improved, but environmental and health problems worsen

Engineering Contradiction:
Improvefirefighting effectivenessVSAvoidenvironmental and health problems
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent converts the inherent limitation of water (high surface tension and poor wettability) into a benefit by using surfactants to modify water's properties. This approach maintains the environmental friendliness of water while achieving the firefighting effectiveness previously only attainable with harmful conventional agents.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent changes the chemical composition parameters of water by adding surfactants, transforming water from an ineffective fire extinguishing agent (due to high surface tension) into an effective one. This parameter change enables water to achieve firefighting effectiveness comparable to conventional agents while avoiding their environmental and health hazards.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The agent effectively extinguishes fires on hydrophobic substances, reduces water consumption, minimizes smoke and emissions, and mitigates environmental and health hazards, offering improved firefighting efficiency and safety.

Implementation Method 1

due to the high surface tension of water (72.8 mN/m, 20° C.), the affinity of water to many substances is very low under normal circumstances. In other words, the wettability of water is low

Methodology Applied
Scientific EffectSurface tension reduction: Surface Tension

Implementation Method 2

the wettability of water is low; thus, it is not easy for water to contact many substances, especially the surface of hydrophobic substances

Methodology Applied
Scientific EffectWetting: Wetting

Implementation Method 3

accelerates temperature reduction of the burning substances

Methodology Applied
Scientific EffectEvaporative cooling: Evaporative Cooler

Implementation Method 4

water can be vaporized rapidly to form steam in flames so as to extinguish fire directly by cooling

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS9901761B2CFC-free and phosphor-free aqueous fire extinguishing agent
Publication Date: 2018.02.27 TAIWAN SURFACTANT CORP
  • US9901761B2 patent drawing
  • US9901761B2 patent drawing
  • US9901761B2 patent drawing

AI summary

The present invention provides a method for extinguishing fire, comprising: (A) preparing a CFC-free and phosphorus-free aqueous fire extinguishing agent using a composition comprising 1-70 wt % of a sulfosuccinic acid ester; 1-30 wt % of a wetting agent; and rest in water; (B) diluting the CFC-free and phosphorus-free aqueous fire extinguishing agent by water to form an aqueous solution; and (C) spraying the aqueous solution to a space containing a burning substance. The present invention not only enhances the wettability and permeability of water, but also increases its affinity to burning substances; accelerates cooling of burning substances; inhibits further combustion; reduces water for firefighting; reduces smoke and emission; mitigates environmental problems caused by haze substances from combustions on the ground and in the air and all possible related health hazards. The CFC-free and phosphorus-free aqueous fire extinguishing agent is biodegradable, non-toxic to human and environment, and easy to use.