CFET Top-Tier Gate Stack With Dipole-First Crystallized High-k

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Solution Overview

Problem

Conventional semiconductor device fabrication methods face challenges in optimizing device performance due to high temperature processes that can damage bottom-tier devices in sequential CFET architectures and the limited dielectric constant of amorphous high-k materials.

Innovation Solution

A dipole-first approach is implemented, forming a dipole layer using materials like yttrium oxide or scandium oxide before the high-k gate dielectric layer, followed by a doped high-k gate dielectric layer that achieves a crystalline phase through annealing, reducing the need for high-temperature processing and enhancing dielectric constant values.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If high temperature processes are used during fabrication, then certain IC components can be formed, but bottom-tier devices may be damaged

Engineering Contradiction:
Improvefabrication process capabilityVSAvoiddamage to bottom-tier devices
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The dipole layer is formed before the high-k gate dielectric layer, allowing the dipole drive-in process to be performed at lower temperatures (below 500°C) before bottom-tier device formation. This preliminary action sequence prevents thermal damage to bottom-tier devices while still achieving the necessary dipole drive-in for threshold voltage control.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The conventional sequence is inverted: instead of forming the high-k gate dielectric first and then adding the dipole layer, the dipole layer is formed first followed by the high-k gate dielectric. This inversion allows the dipole drive-in process to occur at lower temperatures that do not damage bottom-tier devices.

Inventive Principle:
Principle #13The other way round (Inversion)

2Ease of manufacture

If amorphous high-k gate dielectric materials are used, then fabrication is simplified, but the dielectric constant is limited

Engineering Contradiction:
Improvefabrication simplicityVSAvoiddielectric constant
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The gate dielectric material undergoes a phase change from amorphous to crystalline through a controlled annealing process. This parameter change increases the dielectric constant from typical amorphous values to crystalline values (e.g., cubic phase HfO2 with κ>20), improving device performance while maintaining fabrication feasibility.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The high-k gate dielectric material transitions from an amorphous phase to a crystalline phase through thermal annealing. This phase transition significantly enhances the dielectric constant, providing better electrical performance and enabling equivalent oxide thickness scaling without increasing physical thickness.

Inventive Principle:
Principle #36Phase transitions

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach improves device performance by minimizing damage to bottom-tier devices and increasing the dielectric constant of the gate dielectric layer, leading to better electrical performance and ease of equivalent oxide thickness scaling.

Implementation Method 1

forming a dipole layer using materials like yttrium oxide or scandium oxide before the high-k gate dielectric layer

Methodology Applied
Scientific EffectDipole effect:

Implementation Method 2

followed by a doped high-k gate dielectric layer that achieves a crystalline phase through annealing

Methodology Applied
Scientific EffectAnnealing: Annealing

Data Source

PatentUS20240258315A1Dipole-first approach to fabricate a top-tier device of a complementary field effect transistor (CFET)
Publication Date: 2024.08.01 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US20240258315A1 patent drawing
  • US20240258315A1 patent drawing
  • US20240258315A1 patent drawing

AI summary

A dipole layer is formed over a semiconductor channel region. A doped gate dielectric layer is formed over the dipole layer. The doped gate dielectric layer contains an amorphous material. Via an annealing process, the amorphous material of the doped gate dielectric layer is converted into a material with at least partially crystal phases. After the doped gate dielectric layer is converted into the layer with partially crystal phases, a metal-containing gate electrode is formed over the doped gate dielectric layer.