CFx/SVO Cathode Layering for Implantable Battery Energy Density

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Solution Overview

Problem

Existing battery designs for implantable medical devices face challenges in achieving high energy density and discharge rate capabilities while also providing an effective end-of-life indicator, with previous attempts at hybrid cathode materials like CFx/SVO suffering from low packing efficiency or reduced discharge rate.

Innovation Solution

A battery design featuring a cathode with a current collector bonded to alternating layers of sub-fluorinated carbon fluoride (CFx) and silver vanadium oxide (SVO), with the SVO filling bores through the CFx layer, enhancing energy density and discharge rate while providing an end-of-life indicator through a sloped discharge voltage curve.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a three-layer sandwiched design with two SVO outer layers and one CFx center layer is used, then the battery provides good EOL indicator and discharge rate capability, but the packing efficiency is low due to requiring two layers of current collector

Engineering Contradiction:
ImproveEOL indicatorVSAvoidcurrent collector layers
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges the CFx and SVO materials into a single integrated cathode layer rather than using separate layers with current collectors between them. This combines the high energy density function of CFx and the EOL indicator function of SVO into one unified structure, eliminating the need for multiple current collector layers and improving packing efficiency.

Inventive Principle:
Principle #5Merging (Combining)

2Ease of manufacture

If CFx and SVO are physically blended together as one material, then the manufacturing is simplified, but the discharge rate capability is reduced compared to SVO-only cathode

Engineering Contradiction:
Improvecathode fabricationVSAvoiddischarge rate
Core Design Contradiction:
Ease of manufactureVSSpeed

Solution Approach 1:

The patent applies local quality by creating distinct regions within the cathode layer where CFx and SVO are positioned to perform their respective functions optimally. The SVO component is specifically positioned to provide discharge rate capability and EOL indication, while CFx provides energy density, maintaining the discharge performance of SVO-only cathodes while simplifying manufacturing.

Inventive Principle:
Principle #3Local quality

3Use of energy by moving object

If CFx material is used to achieve higher energy density, then the energy density is improved, but the discharge rate capability becomes low and EOL indicator is lost

Engineering Contradiction:
Improveenergy densityVSAvoiddischarge rate
Core Design Contradiction:
Use of energy by moving objectVSSpeed

Solution Approach 1:

The patent uses composite materials by combining CFx and SVO in a single cathode layer. This composite structure allows the battery to achieve the high energy density from CFx while simultaneously maintaining the high discharge rate capability and EOL indicator functionality from SVO, resolving the trade-offs between these parameters.

Inventive Principle:
Principle #40Composite materials

Data Source

PatentUS9985294B2High energy density and high rate Li battery
Publication Date: 2018.05.29 PACESETTER INC
  • US9985294B2 patent drawing
  • US9985294B2 patent drawing
  • US9985294B2 patent drawing

AI summary

A battery includes an anode, an electrolyte, and a cathode. The cathode includes a current collector having a first surface and a second surface opposite the first surface, a first material layer comprising sub-fluorinated carbon fluoride (CFx), and a second material layer comprising silver vanadium oxide (SVO) bonded to the first material layer. The first material layer comprising CFx may also be bonded to a third material layer comprising SVO, and the third material layer is bonded to the first surface of the current collector.