Catalytic Cracking Char Recovery for Energy Reduction

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Solution Overview

Problem

Current processes for catalytically cracking a mixture of pyrolysis effluent and hydrocarbon streams require high energy input and result in significant greenhouse gas emissions, particularly when upgrading biofuels like pyrolysis oil, which is energy-intensive and not environmentally friendly.

Innovation Solution

Recovering and utilizing char generated during the catalytic cracking process to provide energy, either by mixing it with a liquid fuel to create a slurry fuel or drying and burning it, thereby reducing energy consumption and emissions by using a renewable resource.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If high temperatures are used for catalytic cracking of pyrolysis effluent and hydrocarbon streams, then cracking conversion is improved, but energy consumption increases

Engineering Contradiction:
Improvecracking conversionVSAvoidenergy consumption
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent converts the harmful effect of high energy consumption into a benefit by recovering char from the cracking effluent and combusting it to generate heat. This recovered heat is then used to preheat the feed streams entering the catalytic cracking zone, creating a self-sustaining energy system that reduces external energy requirements while maintaining high cracking conversion.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent implements preliminary heating of the feed streams using heat recovered from char combustion before the streams enter the catalytic cracking zone. This preheating action reduces the energy demand of the main cracking process by preparing the feed at elevated temperatures in advance, thereby improving cracking conversion while reducing overall energy consumption.

Inventive Principle:
Principle #10Preliminary action

2Productivity

If conventional catalytic cracking processes are used for upgrading biofuels, then fuel upgrading is achieved, but greenhouse gas emissions increase

Engineering Contradiction:
Improvefuel upgradingVSAvoidgreenhouse gas emissions
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent converts the harmful greenhouse gas emissions into a beneficial resource by capturing char (a carbon-containing byproduct) from the cracking effluent and combusting it to generate process heat. This internal heat generation reduces the need for external fossil fuel combustion, thereby maintaining fuel upgrading productivity while significantly reducing net greenhouse gas emissions.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent creates a self-service energy system where the cracking process itself generates the heat it needs through char combustion. The char produced during cracking is recovered and burned to provide heat for feed preheating, making the process self-sustaining and reducing dependence on external energy sources that would generate additional emissions.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of char as a heat source lowers energy requirements and greenhouse gas emissions in the catalytic cracking zone, enhancing the efficiency and sustainability of the process while utilizing a renewable resource.

Implementation Method 1

burning the dried char

Methodology Applied
Scientific EffectCombustion: Combustion

Implementation Method 2

providing energy to the catalytic cracking zone with the recovered char

Methodology Applied
Scientific EffectExothermic reaction: Exothermic Reaction

Implementation Method 3

a hydrocarbon stream is contacted with a particulate cracking catalyst under conditions that are suitable for converting the relatively high boiling point hydrocarbons to lower boiling point hydrocarbons

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 4

organic biomass, such as wood waste, agricultural waste, etc., is rapidly heated to about 450 to about 600° C. (about 842 to about 1112° F.) in the absence of air using a pyrolysis unit

Methodology Applied
Scientific EffectPyrolysis: Pyrolysis

Implementation Method 5

rapidly heated to about 450 to about 600° C. (about 842 to about 1112° F.) in the absence of air

Methodology Applied
Scientific EffectThermal decomposition: Decomposition (biological)

Implementation Method 6

A portion of the pyrolysis vapor stream is condensed in a condensing system to produce a pyrolysis oil stream

Methodology Applied
Scientific EffectCondensation: Condensation

Data Source

PatentUS10703977B2Processes for reducing the energy consumption of a catalytic cracking process
Publication Date: 2020.07.07 UOP LLC
  • US10703977B2 patent drawing

AI summary

Processes and apparatuses for co-processing pyrolysis effluent and a hydrocarbon stream in which a char produced by the catalytic cracking of the pyrolysis effluent is recovered and utilized to provide energy, such as heat to the catalytic cracking zone. The char can be burned in various combustion zones associated with the catalytic cracking zone. The char is produced from a renewable resource.