Charge-Transport Polymer for Wet-Process Organic EL

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Solution Overview

Problem

Conventional polymer materials used in organic electroluminescent (EL) elements produced by wet processes face challenges in solubility in solvents and curability, limiting their effectiveness in large-screen organic EL displays.

Innovation Solution

A charge transport polymer is developed, featuring terminal groups with a polymerizable functional group and an aromatic hydrocarbon group substituted with an electron-withdrawing substituent, enhancing solubility and curability in wet processes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conventional polymer materials are used in wet processes, then film formation is simplified and cost is reduced, but solubility in solvents and curability are insufficient

Engineering Contradiction:
Improvewet process film formationVSAvoidsolubility and curability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent modifies the chemical structure parameters of the polymer by introducing specific terminal groups (formula P1 with polymerizable functional groups) and controlling the proportion of structural units (3-60 mol %), thereby changing the solubility and curability parameters while maintaining wet process compatibility

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite polymer structure combining specific terminal groups (P1 with polymerizable groups) with the main polymer chain, forming a hybrid material that integrates both the simplicity of conventional polymers and the enhanced properties of specially designed molecular structures

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If polymer materials with improved solubility are used, then wet process characteristics are enhanced, but curability may be compromised

Engineering Contradiction:
Improvesolubility in solventsVSAvoidcurability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent precisely controls the proportion of structural units containing terminal groups P1 (3-60 mol %) to optimize the balance between solubility and curability, using parameter optimization to achieve both improved wet process characteristics and adequate curability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces polymerizable functional groups specifically at the terminal positions of the polymer chains (terminal groups P1), concentrating the curability-enhancing functionality at specific locations while maintaining overall solubility through the designed molecular architecture

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The charge transport polymer improves the solvent resistance and curability of organic layers, enabling the formation of high-quality organic electronic elements, organic EL elements, and display devices suitable for large-screen applications.

Implementation Method 1

the terminal groups include a terminal group P containing a polymerizable functional group

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Data Source

PatentUS12202934B2Charge-transport polymer and organic electronic element
Publication Date: 2025.01.21 RESONAC CORP
  • US12202934B2 patent drawing
  • US12202934B2 patent drawing
  • US12202934B2 patent drawing

AI summary

One embodiment relates to a charge transport polymer containing a molecular chain and terminal groups bonded to the molecular chain, wherein the terminal groups include a terminal group P containing a polymerizable functional group and a terminal group EW containing an aromatic hydrocarbon group substituted with an electron-withdrawing substituent, the terminal group P includes a terminal group represented by formula (P1) shown below, and among the carbon atoms contained in the ring of the aromatic hydrocarbon group, if the carbon atom that is bonded to the molecular chain is numbered 1, and numbers are assigned in order to the adjoining carbon atoms, then the electron-withdrawing substituent is bonded to a carbon atom numbered 1+2n (wherein n is an integer of 1 or greater).