Charge Transporting Film Composition for Electrophotographic Photoreceptors

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Solution Overview

Problem

Existing electrophotographic photoreceptors face issues with abrasion resistance and image quality due to the formation of lumps from fluorine-containing resin particles on the surface layer, leading to uneven cleaning and potential image deterioration.

Innovation Solution

A composition for forming a charge transporting film using a solvent with a dielectric constant of 5.0 or more, combined with specific reactive group-containing compounds and fluorine-containing resin particles, inhibits the aggregation of fluorine-containing resin particles, thereby preventing lump formation and enhancing the dispersion of particles on the surface layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If fluorine-containing resin particles are added to the surface layer to improve abrasion resistance, then abrasion resistance is improved, but particle aggregation occurs leading to lump formation and image quality deterioration

Engineering Contradiction:
Improveabrasion resistanceVSAvoidimage quality
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

A dispersant is introduced as an intermediary substance between the fluorine-containing resin particles and the solvent. The dispersant has a hydrophobic group that interacts with the fluorine-containing resin particles and a hydrophilic group that interacts with the solvent, enabling stable dispersion and preventing particle aggregation that would otherwise occur when fluorine-containing resin particles are simply mixed into the surface layer composition.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the chemical and physical parameters of the dispersion system by selecting a dispersant with specific molecular structure characteristics (hydrophobic-hydrophilic balance) and controlling its concentration within a specific range (0.1-10 parts by weight per 100 parts of fluorine-containing resin). This parameter optimization ensures adequate particle separation without causing excessive foaming or instability.

Inventive Principle:
Principle #35Parameter changes

2Duration of action of stationary object

If fluorine-containing resin particles are dispersed in the surface layer to enhance durability, then durability is improved, but uneven distribution occurs causing cleaning issues and image deterioration

Engineering Contradiction:
ImprovedurabilityVSAvoiduniformity of particle distribution
Core Design Contradiction:
Duration of action of stationary objectVSStability of the object's composition

Solution Approach 1:

The dispersant acts as a mediator that provides steric and electrostatic repulsion between fluorine-containing resin particles. The hydrophobic portions of the dispersant molecules attach to the particle surfaces while the hydrophilic portions extend into the continuous phase, creating a protective barrier that prevents particle aggregation and ensures uniform distribution throughout the surface layer.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention optimizes the concentration of the dispersant within a specific range (0.1-10 parts by weight per 100 parts of fluorine-containing resin). This parameter control ensures sufficient particle separation for uniform distribution while avoiding excessive dispersant that could cause foaming, reduce film formation quality, or create new aggregation mechanisms.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution improves the abrasion resistance and maintains excellent electrical characteristics of the photoreceptor by preventing particle aggregation, ensuring consistent image quality and extended photoreceptor life.

Implementation Method 1

a solvent having a dielectric constant of 5.0 or more

Methodology Applied
Scientific EffectDielectric: Dielectric

Data Source

PatentUS8951701B2Composition for forming charge transporting film, electrophotographic photoreceptor, process cartridge, and image forming apparatus
Publication Date: 2015.02.10 FUJIFILM BUSINESS INNOVATION CORP
  • US8951701B2 patent drawing
  • US8951701B2 patent drawing
  • US8951701B2 patent drawing

AI summary

Provided is a composition for forming a charge transporting film, including a solvent having a dielectric constant of 5.0 or more, at least one kind of compound selected from a group consisting of the following compounds (I-b), (I-c), and (I-d), fluorine-containing resin particles, and a fluorine-containing dispersant, the following compounds (I-b), (I-c), and (I-d) further represented by a compound represented by the following Formula (V)