Chelated Quantum Dot Precursors for Smooth Micro-LED Color Layers

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Solution Overview

Problem

Existing techniques for manufacturing micro-LED displays face challenges in precisely and cost-effectively depositing color conversion agents, such as quantum dots, onto different pixels on a substrate, due to issues with alignment accuracy, resolution, and throughput.

Innovation Solution

A photocurable composition is developed, comprising quantum dots, quantum dot precursor materials, a chelating agent, one or more monomers, and a photoinitiator. This composition is designed to stabilize quantum dot precursor materials and inhibit their aggregation, facilitating the formation of smooth color conversion layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If quantum dot precursor materials are used in color conversion layers, then the ability to convert short wavelength light to longer wavelength light is improved, but metal-containing aggregates form causing particulate defects

Engineering Contradiction:
Improvecolor conversion capabilityVSAvoidparticulate-free quality
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent introduces chelating agents as intermediary substances that bind to metal ions in quantum dot precursor materials. These chelating agents act as mediators that prevent metal ion aggregation while allowing the precursor materials to function in color conversion. The chelating agents form stable complexes with metal ions, preventing them from forming harmful aggregates during the color conversion process.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the chemical environment by introducing chelating agents that change the binding parameters of metal ions. This parameter change transforms the free metal ions into chelated complexes, fundamentally altering their aggregation behavior and preventing particulate formation while maintaining color conversion functionality.

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If chelating agents are added to stabilize quantum dot precursor materials, then aggregation of metal atoms is inhibited, but the composition complexity increases

Engineering Contradiction:
Improveprecursor material stabilityVSAvoidcomposition complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The chelating agents perform multiple functions simultaneously: they stabilize quantum dot precursor materials, prevent metal ion aggregation, and maintain the integrity of the color conversion layer. This multi-functionality reduces the need for additional separate additives or processing steps, thereby limiting the increase in composition complexity while achieving multiple stabilization goals.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Manufacturing precision

If selective deposition techniques are used to deposit color conversion agents, then alignment accuracy is improved, but throughput decreases

Engineering Contradiction:
Improvealignment accuracyVSAvoidthroughput
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent extracts the color conversion capability from the quantum dot precursor materials themselves, allowing them to be deposited as stable precursors that maintain their function without requiring complex selective deposition. The chelating agents enable the precursor materials to be handled and deposited more easily while maintaining precision and enabling higher throughput processing.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the photocurable composition with chelating agents reduces the formation of metal-containing aggregates, resulting in smooth color conversion layers free of particulates, thereby enhancing the manufacturing efficiency and quality of micro-LED displays.

Implementation Method 1

The chelating agent is configured to chelate the quantum dot precursor materials

Methodology Applied
Scientific EffectChelation:

Implementation Method 2

The photoinitiator initiates polymerization of the one or more monomers in response to absorption of radiation in the second wavelength band

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 3

The quantum dots are selected to emit radiation in a first wavelength band in the visible light range in response to absorption of radiation in a second wavelength band in the UV or visible light range

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Data Source

PatentUS12283647B2Chelating agents for quantum dot precursor materials in color conversion layers for micro-LEDs
Publication Date: 2025.04.22 APPLIED MATERIALS INC
  • US12283647B2 patent drawing
  • US12283647B2 patent drawing
  • US12283647B2 patent drawing

AI summary

A photocurable composition includes quantum dots, quantum dot precursor materials, a chelating agent, one or more monomers, and a photoinitiator. The quantum dots are selected to emit radiation in a first wavelength band in the visible light range in response to absorption of radiation in a second wavelength band in the UV or visible light range. The second wavelength band is different than the first wavelength band. The quantum dot precursor materials include metal atoms or metal ions corresponding to metal components present in the quantum dots. The chelating agent is configured to chelate the quantum dot precursor materials. The photoinitiator initiates polymerization of the one or more monomers in response to absorption of radiation in the second wavelength band.