Chemical Looping Integration with CO2 Purification

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Solution Overview

Problem

Chemical looping systems require an external lift gas to facilitate efficient combustion in both the oxidizer and reducer, which can reduce efficiency and increase costs, especially when using steam or product carbon dioxide, and existing solutions add contaminants to flue gases.

Innovation Solution

Integrating a carbon dioxide gas purification unit with a chemical looping system to recycle vent gases as a lift gas, reducing the need for external lift gases and utilizing carbon-bearing compounds to enhance fuel conversion and reduce emissions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If external lift gas is used in the chemical looping system, then efficient combustion is achieved, but the need for external lift gas increases operational costs and reduces overall efficiency

Engineering Contradiction:
Improvecombustion efficiencyVSAvoidoperational efficiency
Core Design Contradiction:
ProductivityVSLoss of energy

Solution Approach 1:

The patent combines the gas purification unit with the chemical looping system by integrating the vent gas recycle loop. The vent gas from the gas purification unit is recycled back to the reducer as lift gas, merging two previously separate functions (combustion support and gas purification) into a unified system that eliminates the need for external lift gas and improves overall operational efficiency

Inventive Principle:
Principle #5Merging (Combining)

2Ease of operation

If steam or product carbon dioxide is used as lift gas, then combustion is facilitated, but additional contaminants are added to the flue gases

Engineering Contradiction:
Improvecombustion facilitationVSAvoidflue gas contaminants
Core Design Contradiction:
Ease of operationVSObject-generated harmful factors

Solution Approach 1:

The patent recovers vent gas that would otherwise be discarded from the gas purification unit and reuses it as lift gas in the reducer. This recovery approach eliminates the need to introduce additional contaminants through external lift gas sources while maintaining effective combustion support

Inventive Principle:
Principle #34Discarding and recovering

Data Source

PatentUS9550680B2Chemical looping integration with a carbon dioxide gas purification unit
Publication Date: 2017.01.24 GENERAL ELECTRIC TECH GMBH
  • US9550680B2 patent drawing
  • US9550680B2 patent drawing
  • US9550680B2 patent drawing

AI summary

A chemical looping system that contains an oxidizer and a reducer is in fluid communication with a gas purification unit. The gas purification unit has at least one compressor, at least one dryer; and at least one distillation purification system; where the gas purification unit is operative to separate carbon dioxide from other contaminants present in the flue gas stream; and where the gas purification unit is operative to recycle the contaminants to the chemical looping system in the form of a vent gas that provides lift for reactants in the reducer.