Chip Active Layer Protection During Substrate Removal

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Solution Overview

Problem

The existing chip-to-plate transfer process for electronic chips, particularly those with type III-V materials, faces issues such as degradation of active layers and residue left from initial substrate removal during grinding, which affects the performance of image sensors due to spectrum absorption problems.

Innovation Solution

A method involving the formation of first and second dielectric encapsulation layers around the chips, followed by directional etching and selective chemical etching of the initial substrate, to protect the active layers during substrate removal, reducing residue and maintaining the integrity of the active layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If the initial substrate is removed by grinding, then the active layer can be accessed, but the active layer is degraded and residues remain

Engineering Contradiction:
Improveactive layer integrityVSAvoidsubstrate residues
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The method applies preliminary protective actions by forming encapsulation layers around the electronic chips before the grinding process. The first encapsulation layer is formed, then grinding is performed, and a second encapsulation layer is formed to protect the edges during subsequent etching steps. This preliminary protection prevents the harmful effects of grinding on the active layer while still allowing substrate removal.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The encapsulation layers serve as intermediary protective structures between the grinding process and the active layer. These dielectric layers absorb the mechanical stress and protection needs, allowing the grinding process to remove the initial substrate without directly contacting and degrading the active layer. The encapsulation layers are selectively removed later through directional etching.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Object-generated harmful factors

If the initial substrate is completely removed by grinding, then no residues remain, but the active layer is degraded

Engineering Contradiction:
Improvesubstrate residuesVSAvoidactive layer integrity
Core Design Contradiction:
Object-generated harmful factorsVSManufacturing precision

Solution Approach 1:

Protective encapsulation layers are formed before the grinding process to shield the active layer. The first encapsulation layer is deposited, then grinding removes the initial substrate completely without degrading the protected active layer. After grinding, a second encapsulation layer is formed to protect the chip edges during subsequent selective etching of any remaining substrate residues.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The encapsulation layers act as intermediary protective barriers during the grinding process. These dielectric layers absorb the mechanical impact and prevent direct contact between the grinding tool and the active layer, enabling complete substrate removal while maintaining active layer integrity. The encapsulation layers are later selectively removed through directional etching.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of manufacture

If directional etching is performed to expose the remaining substrate, then selective chemical etching can be performed, but the second encapsulation layer must be partially removed

Engineering Contradiction:
Improvesubstrate removal efficiencyVSAvoidprocess steps
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

The directional etching process applies local quality by selectively removing portions of the second encapsulation layer based on location. The etching is performed in a directional manner to expose the remaining substrate in specific areas while preserving the encapsulation layer in other areas where protection is still needed. This localized modification enables subsequent selective chemical etching without requiring complete removal of the protective layer.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The encapsulation layer removal is segmented into two distinct phases: first, directional etching removes portions of the second encapsulation layer to expose the substrate in specific areas; second, selective chemical etching removes the exposed substrate while the remaining encapsulation layer continues to protect other areas. This segmentation allows precise control over where substrate removal occurs.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method effectively protects the active layers from degradation and minimizes substrate residues, ensuring the performance of electronic chips, especially image sensors, by using dielectric encapsulation layers and selective etching to remove the initial substrate efficiently.

Implementation Method 1

perform a directional etch of a portion of the second encapsulation layer, extending over the remaining portion of the initial substrate of each of the electronic chips

Methodology Applied
Scientific EffectDirectional etching:

Implementation Method 2

perform a selective chemical etch of the remaining portion of the initial substrate of each of the electronic chips; step f) being carried out with a chemical etching agent allowing selective etching of the remaining portion of the initial substrate with respect to the second encapsulation layer and with respect to the dielectric layer

Methodology Applied
Scientific EffectSelective chemical etching:

Data Source

PatentEP4492459A1Method for protecting active layers of electronic chips
Publication Date: 2025.01.15 COMMISSARIAT A LENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
  • EP4492459A1 patent drawingFigure 1
  • EP4492459A1 patent drawingFigure 2
  • EP4492459A1 patent drawingFigure 3

AI summary

A method for protecting active layers (1) of electronic chips (P), comprising the successive steps: a) using a stack comprising successively: - a support substrate (S1); - a hybrid bonding interface (IC); - electronic chips (P), each comprising successively an active layer (1), a dielectric layer (2) and an initial substrate; b) forming a first encapsulation layer (E1) around the electronic chips (P); c) performing a grinding operation so as to remove a portion of the initial substrate and retain a remaining portion; d) forming a second encapsulation layer (E2) around the electronic chips (P); e) performing a directional etching of a portion of the second encapsulation layer (E2), so as to: - superficially expose the remaining portion of the initial substrate; - retain the second encapsulation layer (E2) extending over the sides of the electronic chips (P);f) perform a selective chemical etching of the remaining portion of the original substrate.;