Chiral Perovskite Nanocrystal Composition for High CPL Efficiency

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Solution Overview

Problem

Current technologies face challenges in developing materials that produce high luminescence dissymmetry g-factors, high photoluminescence quantum efficiency, and narrow spectral emission for circularly polarized luminescence (CPL), which are essential for various applications including information storage, quantum communication, and 3D displays.

Innovation Solution

A composition comprising a nanocrystalline perovskite core with a chiral molecule bonded to its surface, specifically using colloidal formamidinium lead bromide (FAPbBr3) perovskite nanocrystals synthesized with (R)-2-octylamine, which results in high CPL with an average luminescence dissymmetry g-factor and improved photoluminescence quantum efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional materials are used for CPL, then the device complexity is low, but the luminescence dissymmetry g-factor is insufficient

Engineering Contradiction:
Improveluminescence dissymmetry g-factorVSAvoidmaterial composition complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent employs composite materials by combining chiral molecules with perovskite nanocrystals to create a hybrid system that exhibits enhanced circularly polarized luminescence properties. The chiral molecules are surface-functionalized on the perovskite nanocrystals, creating a composite structure that achieves high luminescence dissymmetry g-factors while maintaining manageable device complexity through controlled integration of the two components.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The chiral molecules are specifically positioned on the surface of the perovskite nanocrystals, creating local chiral environments that enhance the CPL properties. This local functionalization approach allows the bulk perovskite material to maintain its excellent optoelectronic properties while the surface region provides the necessary chiral optical activity, thereby achieving high g-factors without requiring complete restructuring of the entire material system.

Inventive Principle:
Principle #3Local quality

2Measurement precision

If chiral molecules are surface-functionalized on perovskite nanocrystals, then the luminescence dissymmetry g-factor increases, but the manufacturing precision requirements increase

Engineering Contradiction:
Improveluminescence dissymmetry g-factorVSAvoidsurface functionalization precision
Core Design Contradiction:
Measurement precisionVSManufacturing precision

Solution Approach 1:

The chiral molecules are introduced during the synthesis process of the perovskite nanocrystals, allowing surface functionalization to occur concurrently with crystal formation. This preliminary action approach ensures uniform distribution and orientation of chiral molecules on the nanocrystal surfaces without requiring subsequent complex surface modification steps, thereby achieving high g-factors while managing manufacturing precision requirements.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The synthesis methodology allows the chiral molecules to self-organize and self-assemble on the perovskite nanocrystal surfaces during the crystallization process. This self-service mechanism reduces the need for precise external control and manual intervention in the surface functionalization process, achieving uniform chiral coverage and high luminescence dissymmetry through spontaneous molecular organization.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves high CPL with enhanced luminescence dissymmetry g-factors and photoluminescence quantum efficiency, making it suitable for advanced applications such as optoelectronic and spintronic devices.

Implementation Method 1

circularly polarized luminescence (CPL) refers to the differential emission of left- or right-circularly polarized light

Methodology Applied
Scientific EffectCircularly polarized luminescence:

Implementation Method 2

the chiral molecule may induce a photoluminescence quantum efficiency greater than 65% and an average luminescence dissymmetry g-factor greater than 0.02

Methodology Applied
Scientific EffectChiral-induced spin selectivity:

Implementation Method 3

the composition is capable of absorbing circularly polarized light

Methodology Applied
Scientific EffectCircular dichroism:

Implementation Method 4

the chiral molecule may induce a photoluminescence quantum efficiency greater than 65%

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Data Source

PatentUS12104106B2Compositions of chiral molecules and perovskite nanocrystals and methods of making the same
Publication Date: 2024.10.01 ALLIANCE FOR ENERGY INNOVATION LLC
  • US12104106B2 patent drawing
  • US12104106B2 patent drawing
  • US12104106B2 patent drawing

AI summary

The present disclosure relates to a composition that includes a nanocrystalline core that includes a perovskite and having an outer surface, and a chiral molecule having a functional group, where the functional group is bonded to a first portion of the outer surface, and the composition is capable of circularly polarized luminescence (CPL). In some embodiments of the present disclosure, the composition is capable of absorbing circularly-polarized light.