Two-Step Enzymatic Hydrolysis for Chitin Extraction

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Solution Overview

Problem

Current enzymatic processes for obtaining chitin from insect cuticles are inefficient due to long reaction times and inadequate deproteinization, which affects the purity and structure of the extracted chitin.

Innovation Solution

A two-step enzymatic hydrolysis process using at least one endopeptidase, with a separation step in between to exclude exopeptidases, is employed to break down insect cuticles, followed by thermal inactivation and filtration to enhance chitin extraction efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If a single-step enzymatic hydrolysis process is used, then the process is simple to operate, but the reaction time is long and deproteinization is inadequate

Engineering Contradiction:
Improveprocess simplicityVSAvoidreaction time
Core Design Contradiction:
Ease of operationVSProductivity

Solution Approach 1:

The patent divides the enzymatic hydrolysis process into two distinct steps: first using broad-specificity proteases (e.g., alcalase, papain) to remove bulk proteins, then using endopeptidases (e.g., subtilisin, thermolysin) for thorough deproteinization. This segmentation allows each enzyme type to target specific protein structures, achieving complete deproteinization while reducing total reaction time from hours to minutes.

Inventive Principle:
Principle #1Segmentation

2Ease of manufacture

If conventional enzymatic processes are used, then the process is easy to implement, but the purity of extracted chitin is insufficient due to inadequate protein removal

Engineering Contradiction:
Improveprocess implementabilityVSAvoidchitin purity
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent introduces a specific intermediary step between initial protease treatment and final chitin extraction: the addition of endopeptidases that specifically target and remove remaining protein contaminants. This intermediary enzymatic treatment acts as a mediator that bridges the gap between simple protease hydrolysis and high-purity chitin extraction, ensuring thorough deproteinization while maintaining process simplicity.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If long reaction times are used for enzymatic hydrolysis, then more complete protein removal is achieved, but production efficiency decreases

Engineering Contradiction:
Improvedeproteinization completenessVSAvoidproduction efficiency
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent changes the enzymatic parameters by introducing endopeptidases with different specificity and catalytic properties alongside broad-specificity proteases. This parameter change in enzyme type and activity allows the system to achieve complete deproteinization in significantly reduced time, transforming the reaction from hours to minutes while maintaining high production efficiency.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method significantly reduces the duration of the hydrolysis process and improves the purity of chitin by effectively removing proteins, maintaining the original structure of chitin closer to its natural form.

Implementation Method 1

a first enzymatic hydrolysis of insect cuticles using at least one endopeptidase

Methodology Applied
Scientific EffectEnzymatic hydrolysis: Hydrolysis

Implementation Method 2

the enzyme or enzymatic composition has a proteolytic activity (protease)

Methodology Applied
Scientific EffectProteolytic activity: Enzyme

Implementation Method 3

followed by thermal inactivation and filtration

Methodology Applied
Scientific EffectThermal inactivation: Heat Treatment

Data Source

PatentEP4077701B1Method for obtaining chitin and/or chitosan using two enzymatic hydrolyses
Publication Date: 2024.05.08 YNSECT
  • EP4077701B1 patent drawingFigure 1~2
  • EP4077701B1 patent drawingFigure 3~4
  • EP4077701B1 patent drawingFigure 5

AI summary

The invention relates to a method for obtaining chitin and/or chitosan from insect cuticles. More particularly, the method according to the present invention comprises a first enzymatic hydrolysis of the insect cuticles using at least one endopeptidase, the separation of the hydrolyzed cuticles resulting from the first enzymatic hydrolysis, of the hydrolysis medium, and a second enzymatic hydrolysis of the hydrolyzed cuticles using at least one endopeptidase, excluding exopeptidase.