Chitosan-Cellulose Composite Leather for Biodegradable Sustainability

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Solution Overview

Problem

Conventional leathers have negative environmental impacts due to deforestation, high carbon footprints, and toxic tanning processes, while faux leathers derived from petrochemicals also pose environmental concerns and lack sustainability, necessitating a sustainable alternative.

Innovation Solution

A leather-like material composed of chitosan, nano- and microfibrillated cellulose, pigments, plasticizers, crosslinkers, and an organic acid, with a process involving mixing, solubilizing, molding, and post-treatment for water resistance, utilizing chitin-derived chitosan and cellulose fibrils to create a biodegradable, eco-friendly substitute.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If conventional leather is used, then aesthetic appeal and durability are achieved, but environmental harm and toxicity increase

Engineering Contradiction:
Improveenvironmental harmVSAvoiddurability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent creates a composite material combining chitosan (from chitin) as the primary matrix with cellulose nanofibrils as reinforcement. This composite structure provides both environmental sustainability and mechanical durability, resolving the contradiction between eco-friendliness and reliability. The cellulose nanofibrils embedded in the chitosan matrix create a robust network that mimics natural leather strength while maintaining biodegradability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical and physical parameters of the base material through crosslinking agents and plasticizers. Crosslinking enhances durability and water resistance, while plasticizers maintain flexibility. These parameter changes allow the material to achieve conventional leather performance characteristics without the environmental harm of animal products and toxic tanning processes.

Inventive Principle:
Principle #35Parameter changes

2Duration of action of stationary object

If plastic-based faux leather is used, then sustainability is improved, but biodegradability and environmental persistence worsen

Engineering Contradiction:
Improvebiodegradation timelineVSAvoidmicroplastic generation
Core Design Contradiction:
Duration of action of stationary objectVSObject-generated harmful factors

Solution Approach 1:

The patent employs naturally derived, biodegradable materials (chitosan and cellulose) that can safely decompose after use. This approach embraces the concept of short-living objects that return to the environment harmlessly, contrasting with persistent plastics. The material is designed to biodegrade completely, eliminating microplastic pollution while maintaining functional performance during its service life.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

By adjusting the molecular weight, degree of deacetylation, and crosslinking density of chitosan, the patent optimizes both the functional durability and biodegradation rate. The material is engineered to maintain stability during use but decompose efficiently after disposal, resolving the contradiction between longevity and biodegradability.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If protein-based materials with chitin reinforcement are used, then sustainability is achieved, but production rate and scalability worsen

Engineering Contradiction:
Improveproduction rateVSAvoidmaterial performance
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent replaces complex 3D printing processes with conventional solution casting and molding techniques. The chitosan-cellulose composite is processed as a solution that can be poured, molded, and dried using standard manufacturing equipment, dramatically increasing production rate while maintaining material performance through controlled fiber alignment and matrix formation.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent optimizes processing parameters including solution concentration, drying temperature, and molding pressure to ensure high-quality material formation during rapid production. These parameter adjustments allow scalable manufacturing without compromising the structural integrity and mechanical properties of the final product.

Inventive Principle:
Principle #35Parameter changes

4Strength

If chitosan-based materials are used, then water resistance is improved, but mechanical strength and flexibility worsen

Engineering Contradiction:
Improvemechanical strengthVSAvoidwater absorption
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent creates a composite where hydrophobic cellulose nanofibrils are dispersed within the chitosan matrix. This composite structure provides both mechanical reinforcement and improved water resistance, as the cellulose network creates physical barriers to water penetration while maintaining structural strength and flexibility.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent adjusts the molecular weight, degree of deacetylation, and crosslinking density of chitosan to optimize the balance between water resistance and mechanical properties. Higher crosslinking improves water resistance but may reduce flexibility, so the patent carefully controls these parameters to achieve the desired balance.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a sustainable, water-resistant, and aesthetically pleasing leather alternative that mitigates environmental challenges associated with conventional and faux leather production, leveraging the properties of chitosan and cellulose to achieve strength, flexibility, and biodegradability.

Implementation Method 1

chitosan-cellulose fibril hybrid composition

Methodology Applied
Scientific EffectHydrogen bonding:

Implementation Method 2

fibrillar cellulose reinforcement

Methodology Applied
Scientific EffectPhysical entanglement:

Implementation Method 3

The material absorbs water readily

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 4

chitosan-cellulose fibril hybrid composition

Methodology Applied
Scientific EffectHydrophilic interaction: Hydrophile

Implementation Method 5

crosslinkers

Methodology Applied
Scientific EffectCovalent bonding: Chemical Bonding

Implementation Method 6

the interaction of the phase-separated layers

Methodology Applied
Scientific EffectPhase separation:

Data Source

PatentUS20240417921A1Imitation leather
Publication Date: 2024.12.19 TOMTEX INC
  • US20240417921A1 patent drawing

AI summary

A leather-like material is disclosed composed of chitosan, bulk reinforcement agents such as microfibrillated cellulose, pigments, plasticizers, crosslinkers, and organic acids with properties making it suitable as a leather substitute material.