Stable Chloramine Production via Static Mixer Segmentation

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Solution Overview

Problem

Conventional oxidizing biocides, such as chloramines, are unstable and rapidly decompose when produced as dilute solutions, leading to reduced efficacy in controlling microbial fouling in industrial water systems due to high chlorine demand and rapid pH drop, necessitating immediate use and limiting their effectiveness.

Innovation Solution

An apparatus that produces a stable oxidizing biocide, specifically chloramine, through in situ production using concentrated reactants and an inline static mixer, allowing for continuous mixing and direct injection into the treatment system, maintaining stability and efficacy.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If chloramines are produced as dilute solutions, then they can be easily applied to water systems, but they rapidly decompose leading to reduced efficacy and stability

Engineering Contradiction:
Improveease of applicationVSAvoidstability of chloramine
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

The apparatus divides the chloramine production process into separate stages: concentrated reactant mixing in a static mixer, followed by controlled dilution in a dilution zone. This segmentation allows the chloramine to be formed in concentrated stable form first, then diluted for application, resolving the contradiction between ease of application and stability

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The apparatus performs preliminary mixing of concentrated ammonia and chlorine reactants in the static mixer before dilution occurs. This preliminary action ensures complete reaction and stable chloramine formation prior to dilution, preventing decomposition that would occur if dilution happened first

Inventive Principle:
Principle #10Preliminary action

2Stability of the object's composition

If chloramines are produced with high concentration, then stability is improved, but rapid pH drop occurs reducing effectiveness

Engineering Contradiction:
Improvestability of chloramineVSAvoidpH drop
Core Design Contradiction:
Stability of the object's compositionVSObject-affected harmful factors

Solution Approach 1:

The apparatus introduces water as an intermediary substance in the dilution zone to gradually dilute the concentrated chloramine solution. This controlled dilution process buffers the pH change, allowing the chloramine to maintain stability while avoiding the harmful rapid pH drop that would occur with direct dilution

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The apparatus controls the dilution parameter by adjusting the water-to-chloramine ratio in the dilution zone. This parameter control allows optimization of both stability and pH maintenance, resolving the contradiction between high concentration stability and pH-related effectiveness

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If conventional dilute chloramine solutions are used, then application is simple, but immediate use is required limiting effectiveness

Engineering Contradiction:
Improveease of applicationVSAvoidduration of chloramine action
Core Design Contradiction:
Ease of operationVSDuration of action of moving object

Solution Approach 1:

The apparatus enables continuous production of chloramine through the static mixer and dilution zone, allowing the biocide to be generated on-demand and applied continuously to the water system. This continuous action eliminates the need for immediate use of pre-prepared solutions, extending the duration of effective biocidal action

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The apparatus ensures the production of a stable chloramine biocide that effectively controls microbial fouling by maintaining stability and persistence within the industrial water system, reducing operational inefficiencies and health risks associated with biofilms and pathogenic bacteria.

Implementation Method 1

The apparatus provides for the composition of the reactants and the conditions for production using concentrated reactants, to convert two liquid solutions from their native chemical form to another, with altered biocidal properties

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentEP2097699B1Use of an apparatus for producing stable chloramine
Publication Date: 2019.06.19 NALCO CO
  • EP2097699B1 patent drawingFigure 1
  • EP2097699B1 patent drawingFigure 2

AI summary

The invention relates to an apparatus for the production of oxidizing biocides. The apparatus can be used as a remote production system where the product is stored use or it can be an in situ production system where the product can be in fluid connection with the system being treated. The preferred product of the system is chloramine, which can be produced in a stable form with this apparatus.