Chlorine Purification Distillation System

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Solution Overview

Problem

Current methods for purifying chlorine gas are costly, energy-inefficient, and pose safety and environmental concerns due to the ineffective removal of nitrogen trichloride and bromine byproducts, which can lead to impurities in downstream processes and increased risks in distillation systems.

Innovation Solution

A distillation system with a vaporizer, distillation tower, reflux condenser, and reboiler is used to purify chlorine gas, reducing nitrogen trichloride and bromine components, while minimizing piping and external condensers, thereby enhancing energy efficiency, safety, and reducing environmental impact.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If traditional distillation systems with external condensers and reboilers are used, then chlorine purification can be achieved, but the system becomes complex, expensive, and energy-inefficient

Engineering Contradiction:
Improvechlorine purificationVSAvoiddistillation system complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent combines the condenser and reboiler into a single integrated distillation column structure, eliminating the need for separate external equipment. The condenser is positioned at the top of the column while the reboiler is at the bottom, with both functions performed within the same vertical structure, thereby reducing system complexity and piping requirements while maintaining purification effectiveness

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The distillation column serves multiple functions simultaneously: it separates chlorine from impurities, condenses vapor at the top, and provides heating at the bottom. This multi-functional design eliminates the need for separate dedicated equipment for each function, reducing overall system complexity and cost

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Manufacturing precision

If traditional distillation systems with long piping are used, then separation can be achieved, but safety risks increase due to more failure points

Engineering Contradiction:
Improveseparation efficiencyVSAvoidsafety
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

By integrating the condenser and reboiler into the distillation column, the patent dramatically reduces the length of piping required in the system. Fewer connection points and shorter pipe runs mean fewer potential failure points and reduced safety risks associated with leakage and contamination, while still achieving effective separation of chlorine from impurities

Inventive Principle:
Principle #5Merging (Combining)

3Device complexity

If nitrogen trichloride is not effectively removed, then the purification process is simpler, but impurities remain in downstream processes

Engineering Contradiction:
Improvepurification processVSAvoidimpurities in downstream processes
Core Design Contradiction:
Device complexityVSObject-generated harmful factors

Solution Approach 1:

The patent utilizes temperature parameter changes throughout the distillation column to selectively remove nitrogen trichloride. By controlling the temperature gradient from the heated reboiler at the bottom to the cooled condenser at the top, nitrogen trichloride is separated at specific temperature zones, effectively removing this harmful impurity while maintaining a relatively simple overall process structure

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies different temperature conditions to different zones of the distillation column: the bottom reboiler zone provides high temperature for vaporization, while the top condenser zone provides low temperature for condensation. This localized temperature control enables selective removal of nitrogen trichloride at appropriate positions in the column, effectively addressing the impurity removal challenge

Inventive Principle:
Principle #3Local quality

4Manufacturing precision

If energy-intensive distillation processes are used, then purification can be achieved, but operational costs increase

Engineering Contradiction:
Improvepurification effectivenessVSAvoidenergy efficiency
Core Design Contradiction:
Manufacturing precisionVSUse of energy by moving object

Solution Approach 1:

The patent implements continuous vapor-liquid contact throughout the distillation column, with vapor rising continuously from the reboiler and condensing continuously at the condenser. This continuous operation maximizes the efficiency of each energy input, achieving effective purification while minimizing wasted energy through sustained, optimized mass and heat transfer throughout the column

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method achieves significant cost savings and energy efficiency while improving safety and reducing environmental concerns by effectively separating chlorine gas from byproducts and minimizing holdup of nitrogen trichloride and bromine components, resulting in a more efficient and safer distillation process.

Implementation Method 1

heating the chlorine supply in the vaporizer to form the vapor

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

condensing the vapor in the reflux condenser to form the condensate

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 3

introducing the vapor into the distillation system to provide purified chlorine gas, a distillate including the liquid chlorine and the bromine component, and a bottoms component including nitrogen trichloride

Methodology Applied
Scientific EffectDistillation: Distillation

Implementation Method 4

heating the condensate in the reboiler, removing the purified chlorine gas from the distillation system, and removing the distillate from the distillation system

Methodology Applied
Scientific EffectThermal decomposition: Decomposition (biological)

Data Source

PatentEP2499090B1Method for purifying a chlorine supply
Publication Date: 2016.10.26 BASF SE
  • EP2499090B1 patent drawingFigure 1
  • EP2499090B1 patent drawingFigure 2
  • EP2499090B1 patent drawingFigure 3

AI summary

This invention provides a method for purifying a chlorine supply that includes a chlorine component, a bromine component, and nitrogen trichloride. The method includes the steps of introducing the chlorine supply into a vaporizer, heating the chlorine supply in the vaporizer to form a vapor, and introducing the vapor into a distillation system to provide purified chlorine gas, a distillate that includes liquid chlorine and the bromine component, and a bottoms component including the nitrogen trichloride. The method also includes the steps of condensing the vapor in a reflux condenser, heating the condensate in a reboiler, removing the purified chlorine gas from the distillation system, and removing the distillate from the distillation system.