Chlorine Test Paper Composition for Stable Colorimetric Detection

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current tap water with excessive chlorine content poses health risks and affects nutrient absorption, food quality, and can produce carcinogens, necessitating a quick and accurate method to detect chlorine levels.

Innovation Solution

A chlorine detection test paper is prepared using a buffer, surfactant, and color developer, involving steps of solution preparation, carrier immersion, and drying, with specific components like citric acid, sodium citrate, and DPD, to generate a purple-red compound proportional to chlorine concentration for accurate detection.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If a chlorine detection test paper is prepared using conventional methods, then the detection function is achieved, but the color response is unstable and not bright enough, affecting detection accuracy

Engineering Contradiction:
Improvedetection accuracyVSAvoidcolor response stability
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent changes the chemical parameters of the detection system by introducing a buffer system (citric acid/sodium citrate or phosphoric acid/sodium phosphate) to control pH, and adding surfactants (Tween 20, Tween 80, Span 80, or polyvinyl pyrrolidone) to modify surface properties. These parameter changes stabilize the color response and enhance brightness, resolving the contradiction between detection accuracy and color response stability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite detection system combining multiple components: color developer (DPD, tetramethylbenzidine, syringaldazine, or vanillin azine), buffer agents, and surfactants. This composite material approach synergistically improves both the stability and brightness of color response, enabling accurate detection across the 0.5-10 mg/L chlorine range.

Inventive Principle:
Principle #40Composite materials

2Measurement precision

If the test paper uses simple components, then the preparation is easy, but the detection range and accuracy are limited

Engineering Contradiction:
Improvedetection accuracyVSAvoidpreparation complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent segments the detection system into distinct functional components: color developer, buffer system, and surfactant. Each component serves a specific function, allowing independent optimization. The color developer provides detection capability, the buffer stabilizes pH for consistent response, and the surfactant enhances wettability and color brightness. This segmentation enables accurate detection while maintaining manageable preparation complexity through standardized immersion and drying steps.

Inventive Principle:
Principle #1Segmentation

3Measurement precision

If the color developer concentration is increased to improve detection sensitivity, then the detection range expands, but the color response becomes less stable

Engineering Contradiction:
Improvedetection sensitivityVSAvoidcolor response stability
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent uses buffer systems to control pH parameters, which stabilizes the color response even at elevated color developer concentrations. The buffer maintains optimal pH conditions for the color reaction, preventing instability while allowing sufficient sensitivity for the 0.5-10 mg/L chlorine detection range.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The surfactant acts as an intermediary substance that mediates between the color developer and the water sample. It improves wettability and distributes the color developer uniformly, enabling stable color responses across different chlorine concentrations without sacrificing sensitivity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The test paper provides a stable and bright color response, allowing users to accurately detect chlorine levels from 0.5 mg/L to 10 mg/L by comparing with a color card, ensuring water safety and quality.

Implementation Method 1

the color developer reacts with active chlorine in water to generate a purple-red compound, the color depth of which is proportional to the chlorine concentration

Methodology Applied
Scientific EffectColorimetric reaction:

Implementation Method 2

the buffer can improve the color response of the color developer to free available chlorine and provide a more stable color response

Methodology Applied
Scientific EffectBuffering:

Implementation Method 3

the surfactant helps the test sample to wet the carrier without adversely affecting the color transition of the color developer

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Implementation Method 4

taking out the carrier from the second solution, and drying the carrier to obtain a first test paper

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS20250369945A1Chlorine Detection Test Paper and Preparing Method Thereof
Publication Date: 2025.12.04 YU LILI
  • US20250369945A1 patent drawing
  • US20250369945A1 patent drawing
  • US20250369945A1 patent drawing

AI summary

A chlorine detection test paper includes a carrier and a chlorine detection substance provided on the carrier, wherein the chlorine detection substance contain a color developer which includes one or more of DPD, tetramethylbenzidine, syringaldehyde azine, and vanillin azine.