Cholesteric Liquid Crystal Image Material with Alignment Angle Variation

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Solution Overview

Problem

Existing image recording methods using ink containing liquid crystal compounds do not effectively achieve a stereoscopic effect, which is required for certain applications.

Innovation Solution

An image recorded material and method utilizing a cholesteric liquid crystal layer with a specific stripe pattern and alignment angles, applied using an ink jet recording method and cured with active energy rays, to achieve a stereoscopic effect.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If a cholesteric liquid crystal layer with a stripe pattern is used, then wavelength-selective reflectivity is achieved, but a stereoscopic effect cannot be obtained

Engineering Contradiction:
Improvewavelength-selective reflectivityVSAvoidstereoscopic effect
Core Design Contradiction:
Illumination intensityVSAdaptability or versatility

Solution Approach 1:

The patent applies local quality by creating multiple regions within the cholesteric liquid crystal layer, each with different alignment angles (first alignment angle and second alignment angle). This local variation in alignment properties allows different regions to reflect light at different angles, thereby achieving both wavelength-selective reflectivity and stereoscopic effect simultaneously.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent introduces asymmetry by having the first and second alignment angles be different from each other. This asymmetric alignment structure creates regions that respond differently to light from various viewing angles, enabling the stereoscopic effect while maintaining the wavelength-selective reflectivity characteristic of cholesteric liquid crystals.

Inventive Principle:
Principle #4Asymmetry

2Ease of manufacture

If a uniform cholesteric liquid crystal layer is used, then manufacturing is simple, but a stereoscopic effect cannot be achieved

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidstereoscopic effect
Core Design Contradiction:
Ease of manufactureVSAdaptability or versatility

Solution Approach 1:

Rather than creating a completely uniform layer, the patent introduces controlled local variations in alignment angle within the cholesteric liquid crystal layer. This approach maintains the overall simplicity of the liquid crystal layer structure while introducing specific regional differences that enable the stereoscopic effect.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent segments the cholesteric liquid crystal layer into multiple regions with different alignment angles. This segmentation allows the layer to maintain ease of manufacture as a single liquid crystal layer while achieving the stereoscopic effect through the differentiated alignment properties of its segments.

Inventive Principle:
Principle #1Segmentation

3Device complexity

If the alignment angle is kept constant throughout the layer, then the structure is simple, but viewing angle dependence is limited

Engineering Contradiction:
Improvealignment angle uniformityVSAvoidviewing angle dependence
Core Design Contradiction:
Device complexityVSAdaptability or versatility

Solution Approach 1:

The patent introduces asymmetry in the alignment angle distribution by defining multiple regions with different alignment angles (first alignment angle and second alignment angle). This asymmetric configuration creates viewing angle dependence in different regions, allowing the image to be viewed from multiple angles while maintaining a relatively simple overall layer structure.

Inventive Principle:
Principle #4Asymmetry

Solution Approach 2:

The patent applies local quality by varying the alignment angle in different regions of the cholesteric liquid crystal layer. This local variation in alignment properties enables viewing angle dependence without requiring complex overall structure, as each region independently contributes to the viewing characteristics.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a noticeable stereoscopic effect by creating regions with significant differences in alignment angles and film thickness, enhancing the perceived three-dimensionality of the image.

Implementation Method 1

Cholesteric liquid crystals prepared by adding a chiral agent to the liquid crystal compound have unique light reflectivity and have characteristics in that tone changes depending on the viewing angle

Methodology Applied
Scientific EffectCholesteric liquid crystal: Cholesteric Liquid Crystal

Implementation Method 2

cholesteric liquid crystal layer having wavelength-selective reflectivity

Methodology Applied
Scientific EffectLight reflectivity: Reflection

Implementation Method 3

applying an ink containing a polymerizable liquid crystal compound, a chiral compound, and a solvent onto a substrate by an ink jet recording method

Methodology Applied
Scientific EffectInk jet recording:

Implementation Method 4

irradiating the ink applied onto the substrate with an active energy ray to record an image which is a cured film of the ink

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Data Source

PatentUS12305044B2Image recorded material and image recording method
Publication Date: 2025.05.20 FUJIFILM CORP
  • US12305044B2 patent drawing
  • US12305044B2 patent drawing
  • US12305044B2 patent drawing

AI summary

Provided are an image recorded material including a substrate and an image recorded on the substrate, in which the image includes a cholesteric liquid crystal layer, the cholesteric liquid crystal layer has a stripe pattern of a bright portion and a dark portion, observed by a scanning electron microscope, in a cross section along a thickness direction of the image, in a case where an angle between a continuous line which is the bright portion or the dark portion and a main surface of the substrate is defined as an alignment angle, at least two regions in which an absolute value of a difference of the alignment angles is 5° or more are provided, and both of the two regions have a length of width of 1 mm or more in an in-plane direction of the substrate; and applications thereof.