Responsive Coating for Chromatography Leak Detection and Sealing

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Solution Overview

Problem

Chromatography systems face difficulties in detecting and preventing leaks, especially at low flow rates where leaks are small and difficult to identify, as existing methods require significant fluid volumes or cannot detect vapor leaks.

Innovation Solution

A coating with a responsive material is applied to components of the chromatography system, which changes physical properties such as stiffness in response to fluid contact, allowing for leak detection and prevention by forming a sealant layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional leak detection methods are used, then large leaks can be detected, but small leaks at low flow rates cannot be detected

Engineering Contradiction:
Improveleak detection sensitivityVSAvoidfluid volume required for detection
Core Design Contradiction:
Measurement precisionVSQuantity of substance

Solution Approach 1:

The patent applies parameter changes by utilizing the responsive material's ability to change physical properties (such as swelling, softening, or changing refractive index) in response to fluid contact. This allows the coating to detect even trace amounts of fluid leakage, transforming the detection threshold from requiring significant fluid volumes to detecting minimal fluid presence through physical property changes of the coating material itself.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs color changes as a detection mechanism where the responsive material within the coating changes its optical properties (color, fluorescence, or refractive index) upon contact with leaking fluid. This visual transformation enables detection of small leaks without requiring large fluid volumes, as the coating itself becomes the indicator through its physical property changes.

Inventive Principle:
Principle #32Color changes

2Reliability

If sealing components are made more complex to prevent leaks, then leak prevention improves, but device complexity increases

Engineering Contradiction:
Improveleak prevention capabilityVSAvoidsystem component complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies self-service by enabling the coating to autonomously respond to fluid contact and seal leaks without external intervention. The responsive material automatically changes its physical properties upon detecting fluid, creating a self-healing seal that prevents further leakage. This eliminates the need for complex external sealing mechanisms, pressure relief systems, or manual leak detection and repair procedures.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent utilizes flexible shells and thin films by applying a coating layer containing responsive material directly onto system components. This thin film approach provides leak prevention and detection functionality without adding bulky sealing components or complex mechanical structures. The coating conforms to the surface topology and provides flexible sealing that adapts to thermal expansion and pressure changes.

Inventive Principle:
Principle #30Flexible shells and thin films

3Difficulty of detecting and measuring

If traditional leak detection sensors are used, then detection is possible, but vapor leaks and small leaks are missed

Engineering Contradiction:
Improvedetectability of small and vapor leaksVSAvoidminimum fluid volume for detection
Core Design Contradiction:
Difficulty of detecting and measuringVSQuantity of substance

Solution Approach 1:

The patent applies preliminary action by having the responsive coating continuously present and ready on system surfaces before leaks occur. The coating is pre-positioned in strategic locations where leaks are most likely to happen, maintaining constant surveillance capability. When fluid or vapor leaks occur, the coating immediately responds through physical property changes, detecting leaks at their inception rather than requiring accumulation of significant fluid volumes.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent replaces mechanical detection systems (such as pressure sensors, flow meters, or visual inspection) with a chemical-physical response system. The responsive material undergoes physical property changes (swelling, softening, color change, refractive index change) upon contact with fluid or vapor, providing detection capability for both liquid and vapor leaks without requiring mechanical sensing elements or significant fluid accumulation.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables the identification of smaller leaks and prevents fluid passage by creating a sealant barrier, improving the accuracy and safety of chromatography systems by detecting leaks before significant fluid loss occurs.

Implementation Method 1

The responsive material is disposed to change at least one physical property. The responsive material is a physically responsive material that becomes stiffer in order to stop or reduce a leak

Methodology Applied
Scientific EffectResponsive material physical change:

Implementation Method 2

A coating with a responsive material is applied to components of the chromatography system, which changes physical properties such as stiffness in response to fluid contact

Methodology Applied
Scientific EffectPhysical property change response:

Implementation Method 3

prevents fluid passage by creating a sealant barrier

Methodology Applied
Scientific EffectSealant layer formation:

Data Source

PatentEP3571484B1Systems, methods, and devices for stopping or reducing leaks in a chromatography system
Publication Date: 2024.10.09 WATERS TECHNOLOGY CORP
  • EP3571484B1 patent drawingFigure 1
  • EP3571484B1 patent drawingFigure 2~3
  • EP3571484B1 patent drawingFigure 4

AI summary

Systems, methods, and devices for detecting leaks in chromatography systems are disclosed. A coating is disposed to conform to at least one component of a chromatography system, such as a fitting or a section of tubing. The coating is made of or contains a responsive material that can undergo a detectable change when exposed to a chromatographic fluid or mobile phase. The change of the responsive material can indicate the presence of the fluid or mobile phase, a change in at least one physical property of the coating to prevent passage of the fluid or mobile phase, or a combination thereof.