Chromium Oxide Half Mirror Thermal Resistance

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Solution Overview

Problem

Conventional half mirrors used in lighting applications, such as vehicle lamps and lighting apparatuses, suffer from instability in reflectivity and appearance due to cracking under temperature fluctuations and high-intensity light sources, leading to reduced durability and longevity.

Innovation Solution

A half mirror design featuring a chromium oxide layer with a specific oxygen-to-chromium ratio, applied using a sputtering method with controlled argon gas pressure and power, is used to enhance thermal resistance and prevent cracking, while maintaining stable reflectivity and appearance over time.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If chromium is coated on the lens using sputtering method, then the half mirror can be manufactured, but small cracks occur when heat-shocked by repeating low temperature and high temperature

Engineering Contradiction:
Improvethermal resistanceVSAvoidcrack resistance
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent applies composite materials by forming a multi-layer structure consisting of a chromium oxide layer and a chromium layer. The chromium oxide layer (5-20 nm thick) serves as a buffer layer with different thermal expansion properties compared to the chromium layer (10-50 nm thick) and the lens substrate. This composite structure absorbs thermal stress during temperature cycling, preventing crack formation while maintaining the half mirror's reflective functionality.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the chemical composition and physical properties of the coating by controlling the oxidation state of chromium. By forming chromium oxide (Cr2O3) instead of pure chromium metal through controlled oxidation during sputtering, the material exhibits different thermal expansion coefficients and adhesion properties. This parameter change in the material's chemical state resolves the thermal shock resistance issue.

Inventive Principle:
Principle #35Parameter changes

2Illumination intensity

If high-intensity light source such as laser device is used, then lighting performance is improved, but qualities of the half mirrors are degraded

Engineering Contradiction:
Improvelight emitting intensityVSAvoidhalf mirror quality
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The multi-layer composite structure of chromium oxide and chromium provides enhanced resistance to high-intensity light degradation. The chromium oxide layer acts as a protective barrier that is more resistant to photodegradation and thermal damage from high-power laser sources, while the chromium layer maintains the optical reflective properties. This composite approach allows the half mirror to withstand high illumination intensity without quality degradation.

Inventive Principle:
Principle #40Composite materials

3Reliability

If conventional materials such as silver, aluminum, or multi-layer interference layer are used, then reflectivity is achieved, but thermal resistance and crack prevention are insufficient

Engineering Contradiction:
ImprovedurabilityVSAvoidreflectivity stability
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent changes the material parameter from conventional reflective coatings (silver, aluminum, or multi-layer interference structures) to a chromium-based oxide layer. Chromium oxide provides both the necessary optical reflective properties and superior thermal stability. The specific oxygen-to-chromium ratio is controlled to optimize both the thermal resistance and reflectivity, achieving a balance between durability and optical performance that conventional materials cannot provide.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The chromium oxide layer provides high thermal resistance and durability, preventing cracking under varying temperatures and ensuring long-term stable reflectivity and appearance in lighting units, including vehicle lamps and other applications.

Implementation Method 1

formed on at least one of the first surface and the second surface of the base material as a chromium oxide layer

Methodology Applied
Scientific EffectSputtering: Sputtering

Implementation Method 2

provides high thermal resistance and durability, preventing cracking under varying temperatures

Methodology Applied
Scientific EffectThermal resistance: Thermal Insulation

Data Source

PatentUS10429554B2Half mirror, method for manufacturing the same and lighting unit using the same
Publication Date: 2019.10.01 STANLEY ELECTRIC CO LTD
  • US10429554B2 patent drawing
  • US10429554B2 patent drawing
  • US10429554B2 patent drawing

AI summary

A half mirror, a method for manufacturing the half mirror and a lighting unit using the half mirror can include a base material and a half mirror layer formed on the base material. The half mirror layer can include a chrome oxide layer, which is made by only a sputtering method, and can be configured to perform a high thermal resistance. Accordingly, the half mirror cannot crack even under various circumstances such that repeat low/high temperatures. Thus, the disclosed subject matter can provide half mirrors having a high durability such as a thermal resistance and methods for manufacturing such the half mirrors in simple manufacturing processes, and also can provide lighting units using the half mirror having a high durability, which can maintain a stable reflectivity for a long term and which can also maintain a good appearance for a long-term use because the half mirror can prevent cracking therein.