Chrysene-Silyl Compound for Solution-Processed OLED Coating

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Solution Overview

Problem

The existing deposition process for manufacturing organic light emitting devices results in high material loss and inefficiency, requiring the development of materials suitable for a solution process that can form stable, homogeneous solutions and thin films with uniform thickness, excellent coatability, and improved lifetime and current efficiency.

Innovation Solution

A compound represented by Chemical Formula 1, which includes a chrysene core structure with a silyl group, is used in a coating composition to form organic material layers, enabling the manufacturing of organic light emitting devices through a solution process, reducing material loss, and enhancing solubility, driving voltage, light efficiency, and thermal stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If a deposition process is used to manufacture organic light emitting devices, then device performance can be achieved, but material loss is high and production efficiency is low

Engineering Contradiction:
Improvematerial lossVSAvoidproduction efficiency
Core Design Contradiction:
Loss of energyVSProductivity

Solution Approach 1:

The patent replaces the mechanical deposition process with a solution-based coating process. The compound is dissolved in a solvent to form a coating composition that can be applied via solution processing methods, eliminating the material loss and inefficiency associated with traditional deposition techniques while enabling scalable manufacturing

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Stability of the object's composition

If commercialized materials for deposition process are used, then favorable crystallinity is achieved, but solubility is poor and homogeneous solution formation is difficult

Engineering Contradiction:
ImprovecrystallinityVSAvoidsolubility
Core Design Contradiction:
Stability of the object's compositionVSQuantity of substance

Solution Approach 1:

The patent creates a composite molecular structure by combining a chrysene core (providing crystallinity and light-emitting properties) with silyl groups (providing solubility). This composite approach allows the material to simultaneously achieve favorable crystallinity for device performance and sufficient solubility for solution processing

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies local quality modification by introducing silyl groups at specific positions on the chrysene core structure. The chrysene core maintains its crystalline properties while the silyl substituents provide the necessary solubility, allowing different parts of the molecule to fulfill different functional requirements

Inventive Principle:
Principle #3Local quality

3Productivity

If a solution process is used to manufacture organic light emitting devices, then production efficiency increases and material loss decreases, but uniform thin film formation without holes or aggregation is challenging

Engineering Contradiction:
Improveproduction efficiencyVSAvoidthin film uniformity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent optimizes parameters including solvent selection, compound concentration in the coating composition, and coating conditions to achieve uniform thin film formation. The molecular structure is designed with appropriate solubility characteristics that enable homogeneous solution formation and uniform film deposition without aggregation or hole formation

Inventive Principle:
Principle #35Parameter changes

4Productivity

If a solution process is used, then manufacturing efficiency improves, but materials must form storable homogeneous solutions which is difficult for crystalline materials

Engineering Contradiction:
Improvemanufacturing efficiencyVSAvoidsolution homogeneity
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The patent designs a composite molecular structure combining chrysene core with silyl groups, where the silyl substituents provide the necessary solubility characteristics to form stable, homogeneous solutions that can be stored and processed without precipitation or aggregation, enabling solution-based manufacturing

Inventive Principle:
Principle #40Composite materials

Data Source

PatentUS11299503B2Compound, coating composition comprising the same, organic light emitting device using the same and method for manufacturing the same
Publication Date: 2022.04.12 LG CHEM LTD
  • US11299503B2 patent drawing
  • US11299503B2 patent drawing
  • US11299503B2 patent drawing

AI summary

The present specification relates to a compound represented by Chemical Formula 1, a coating composition comprising the compound, an organic light emitting device formed using the coating composition, and a method for manufacturing the same.