Copper Indium Gallium Sulfide Quantum Dot Core-Shell Structure

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Solution Overview

Problem

Existing display devices face challenges in achieving improved color reproductivity and light absorption properties, particularly in light-emitting elements using quantum dots.

Innovation Solution

A quantum dot with a core containing copper, gallium, indium, and sulfur, and a method for preparing it by forming a mixture of precursors and solvents, followed by thermal reactions to achieve a core diameter of about 3 nm to 6 nm and a shell structure for enhanced properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional quantum dots are used in light-emitting elements, then the display device can be manufactured with standard materials, but the color reproductivity and light absorption properties are insufficient

Engineering Contradiction:
Improvecolor reproductivityVSAvoidmanufacturing complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent employs composite materials by combining copper, gallium, indium, and sulfur to form a core structure with enhanced optical properties. This composite core is further encapsulated with zinc and sulfur shells, creating a multi-layered quantum dot structure that achieves improved color reproductivity and light absorption characteristics while maintaining manufacturability through established chemical synthesis methods

Inventive Principle:
Principle #40Composite materials

2Reliability

If the core diameter is increased to improve light absorption, then light absorption properties enhance, but the emission efficiency and color reproductivity may deteriorate

Engineering Contradiction:
Improvelight absorption propertiesVSAvoidemission efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent optimizes the core diameter parameter to a specific range of 3-6 nm, which balances light absorption capabilities with emission efficiency. This precise parameter control, combined with the multi-shell structure, enables the quantum dot to achieve both improved light absorption and maintained emission efficiency, resolving the contradiction between these two performance aspects

Inventive Principle:
Principle #35Parameter changes

3Duration of action of stationary object

If a multi-shell structure is added to enhance stability, then the lifespan improves, but the manufacturing process becomes more complex

Engineering Contradiction:
ImprovelifespanVSAvoidstructure complexity
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The patent applies the nested doll principle by creating a core-shell structure where a zinc and sulfur shell encapsulates the copper-gallium-indium-sulfur core. This nested configuration provides enhanced stability and extended lifespan while maintaining a relatively simple two-stage synthesis process, thus improving durability without excessively increasing manufacturing complexity

Inventive Principle:
Principle #7Nested doll (Nesting)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The quantum dot exhibits improved color reproductivity and light absorption properties, leading to enhanced emission efficiency and stability in display devices.

Implementation Method 1

reacting the fourth mixture at a first temperature for about 5 minutes to about 15 minutes, and the first temperature may be about 250° C. to about 350° C.

Methodology Applied
Scientific EffectThermal decomposition: Pyrolysis

Data Source

PatentUS20250084306A1Quantum dot and method for preparing the quantum dot
Publication Date: 2025.03.13 SAMSUNG DISPLAY CO LTD
  • US20250084306A1 patent drawing
  • US20250084306A1 patent drawing
  • US20250084306A1 patent drawing

AI summary

A method for preparing a quantum dot and a quantum dot are provided. The method for preparing a quantum dot includes supplying a first mixture including a first precursor containing gallium oleate, a second precursor containing indium oleate, and a third precursor containing a sulfur atom, forming a second mixture by adding a first solvent to the first mixture, and forming a fourth mixture including a core containing a copper atom, an indium atom, a gallium atom, and a sulfur atom by adding a third mixture containing copper to the second mixture.