CIGS Solar Cell Precursor Compound for Room-Temperature Solution Processing
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Solution Overview
Problem
CIGS thin film solar cells are not economical due to high process costs and the instability of metal-dithiocarbamate solutions used in their fabrication.
Innovation Solution
A precursor compound containing copper, sulfur, and indium or gallium, formed by reacting a copper precursor with a sulfide-based organic material, such as diethyldithiocarbamate, in a solution to create a copper complex compound, which is then mixed with a metal halide, allowing for the production of a photoactive layer at room temperature without the need for vacuum deposition equipment.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Loss of energy
If CIGS thin film is synthesized in high vacuum, then high efficiency solar cell is produced, but process cost becomes high
Solution Approach 1:
The patent replaces the mechanical vacuum deposition system with a solution-based chemical synthesis approach. The precursor compound dissolves in solvent to form a solution that can be deposited by simple coating methods, eliminating the need for expensive vacuum equipment while maintaining high efficiency through controlled chemical reactions that form the CIGS photoactive layer.
Solution Approach 2:
The patent changes the physical state of the precursor from solid (requiring vacuum deposition) to dissolved solution (enabling liquid-phase processing). This parameter change allows the use of low-cost coating techniques such as spin-coating or dip-coating instead of expensive vacuum deposition, significantly reducing manufacturing costs while preserving the ability to form high-efficiency CIGS films.
2Ease of manufacture
If metal-dithiocarbamate solution is used for fabricating photoactive layer, then fabrication is simplified, but solution stability becomes poor
Solution Approach 1:
The patent performs preliminary action by pre-synthesizing a stable precursor compound containing metal, dithiocarbamate, and halogen in a specific molecular structure before solution formation. This pre-organized molecular structure with defined stoichiometry prevents premature decomposition or unwanted reactions in solution, maintaining stability while preserving the simplified fabrication advantages of solution processing.
Solution Approach 2:
The patent creates a composite molecular structure where metal, dithiocarbamate ligand, and halogen are combined into a single stable precursor compound. This composite structure integrates multiple functional components (metal source, sulfur source, and halogen) into one stable molecule that can be handled in solution without the instability problems of separate metal-dithiocarbamate complexes.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
This method enables the production of high-efficiency solar cells at a lower cost by simplifying the synthesis of metal complexes and facilitating large-area production, while avoiding the use of volatile and toxic materials.
Implementation Method 1
reacting a copper precursor and a sulfide-based organic material in a solution to form a copper complex compound
Data Source
AI summary
Disclosed a precursor compound for producing a photoactive layer of a thin film solar cell that may be used as a precursor of a CIS, CGS or CIGS thin film that may be used as a photoactive layer of a solar cell, and a production method thereof. The precursor compound is represented by a following Chemical Formula 1:wherein, in the Chemical Formula 1, X represents indium (In) or gallium (Ga), Y represents chlorine (Cl) or iodine (I), each of R1, R2, R3 and R4 independently represents a methyl group, a propyl group or an alkyl group having 2 to 10 carbon atoms.


