CIP Chlorine Control Across Broad pH Ranges

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Solution Overview

Problem

Existing CIP systems face challenges in maintaining consistent and accurate chlorine concentrations across a broad pH range due to variability in water quality and pH, which affects the sensitivity and accuracy of chlorine sensors, making it difficult to use electrolytic solutions effectively for cleaning and sanitizing without causing corrosion.

Innovation Solution

A control system that includes an electrochemical cell for in situ production of electrolyzed solution concentrate, a sensing cell with a chlorine sensor and pH probe for measuring and adjusting chlorine oxyanion concentration, and a feedback loop mechanism to maintain chlorine levels between 10 ppm to 1000 ppm and pH between 5.5 and 7.5, ensuring accurate and reproducible chlorine output.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If electrolysis solutions are used for CIP applications to achieve high chlorine concentrations for effective cleaning and sanitizing, then cleaning and sanitizing efficacy is improved, but chlorine levels become corrosive to CIP systems and sensor accuracy deteriorates

Engineering Contradiction:
Improvecleaning and sanitizing efficacyVSAvoidcorrosion and sensor inaccuracy
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The system dynamically adjusts the pH parameter of the electrolysis solution to optimize the chlorine sensor's operating range. By controlling pH levels, the system maintains accurate chlorine measurements while preserving the high chlorine concentrations necessary for effective cleaning and sanitizing, thereby preventing corrosion and ensuring reliable operation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The system employs a feedback mechanism where the chlorine sensor continuously monitors chlorine levels and the pH controller adjusts pH based on sensor readings and setpoint comparisons. This closed-loop control ensures that chlorine concentrations remain within the optimal range for both cleaning efficacy and sensor accuracy, preventing harmful corrosion effects

Inventive Principle:
Principle #23Feedback

2Adaptability or versatility

If pH variability in water supply and dilution water is allowed, then system flexibility is maintained, but chlorine measurement accuracy deteriorates

Engineering Contradiction:
Improvesystem flexibilityVSAvoidchlorine measurement accuracy
Core Design Contradiction:
Adaptability or versatilityVSMeasurement precision

Solution Approach 1:

The pH controller uses feedback from pH sensors to continuously adjust and stabilize pH levels within the optimal range for chlorine measurement. This feedback mechanism maintains measurement accuracy despite variations in water supply pH, while the system remains flexible in accepting different water sources

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The system dynamically adjusts the pH parameter counteracting variations from water supply and dilution water. By actively controlling pH within the sensor's optimal range, the system maintains measurement accuracy while preserving flexibility in water source selection through automated compensation

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system provides consistent and accurate control of chlorine oxyanion concentrations, enabling effective use of electrolyzed water solutions for CIP applications by stabilizing pH and adjusting chlorine levels, thus enhancing cleaning and sanitizing efficacy while preventing corrosion of CIP systems.

Implementation Method 1

Onsite chemistry production can be achieved through electrolysis of water and electrolytes to produce alkaline detergent solutions of sodium hydroxide (NaOH), hypochlorite solutions or chlorine for use as detergent, bleach, surface sanitizers and other disinfectant purposes.

Methodology Applied
Scientific EffectElectrolysis: Electrolysis

Implementation Method 2

The sensing cell (14) comprises a chlorine sensor to measure chlorine oxyanion concentration of the portion of the electrolysis solution in the sensing cell (14)

Methodology Applied
Scientific EffectElectrochemical detection:

Implementation Method 3

a pH probe to determine the pH of the portion of electrolysis solution in the sensing cell (14) that is measured by the chlorine sensor

Methodology Applied
Scientific EffectpH measurement:

Implementation Method 4

a sensing cell signal feedback (18) in communication with the sensing cell (14) and the electrolyzed concentrate control (24) and the dilution water control (26) to control the electrolyzed solution concentrate (10) and the dilution water (28)

Methodology Applied
Scientific EffectFeedback control: Feedback

Data Source

PatentEP2587945B1A CIP cleaning apparatus and a measuring and controlling method for use in said apparatus
Publication Date: 2018.05.02 ECOLAB USA INC
  • EP2587945B1 patent drawingFigure 1
  • EP2587945B1 patent drawingFigure 2
  • EP2587945B1 patent drawingFigure 3

AI summary

Control systems for use of electrolysis solutions for automated recirculating or single-pass cleaning systems, such as clean-in-place (CIP) applications are disclosed. Control systems and methods for using automated chlorine output solutions for various cleaning applications are measurable over broad pH ranges. The control systems generate consistent and predictable electrolytic solutions and include a measurement system that identifies chlorine oxyanion concentration across broad ranges of pH, overcoming the sensitivity of chlorine monitors to pH and permitting use of the control systems to control cleaning systems.