Circulating Fluidized Bed for Continuous Ion Exchange

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Solution Overview

Problem

Existing ion exchange systems face inefficiencies in continuous operation, particularly in particle regeneration and fluid consumption, with previous designs resulting in low ion exchange efficiency and significant dilution of process streams.

Innovation Solution

A vertically arranged liquid-solids circulating fluidized bed (VA-LSCFB) system with counter-current particle and fluid flow in two interconnected columns, allowing continuous counter-current separation and regeneration of ion exchange particles, minimizing fluid consumption and dilution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If a conventional fluidized bed system is used for continuous ion exchange, then continuous operation is achieved, but particle regeneration efficiency is low and large processing volumes are required

Engineering Contradiction:
Improvecontinuous ion exchange efficiencyVSAvoidprocessing volume
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The system is divided into two separate columns: Column 1 for ion exchange and Column 2 for particle regeneration. This segmentation allows each column to be optimized for its specific function, enabling continuous operation with reduced processing volume compared to a single large-scale system.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The system maintains continuous ion exchange by continuously circulating particles between Column 1 and Column 2. While particles are regenerated in Column 2, fresh particles continuously replace them in Column 1, ensuring uninterrupted ion exchange operation without requiring large batch processing volumes.

Inventive Principle:
Principle #20Continuity of useful action

2Ease of operation

If mixed reactors are used for ion exchange, then the system is simple and easy to control, but ion exchange efficiency is low and large processing volumes are essential

Engineering Contradiction:
Improvesystem control simplicityVSAvoidion exchange efficiency
Core Design Contradiction:
Ease of operationVSProductivity

Solution Approach 1:

The system segments the ion exchange process into two distinct functional columns, maintaining operational simplicity through clear functional separation while dramatically improving ion exchange efficiency by eliminating the mixing limitations of single-tank systems.

Inventive Principle:
Principle #1Segmentation

3Productivity

If a vertically arranged liquid-solids circulating fluidized bed system is used, then ion exchange efficiency is improved and fluid consumption is reduced, but system complexity increases

Engineering Contradiction:
Improveion exchange efficiencyVSAvoidsystem structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The system extracts the particle regeneration function from the ion exchange column and places it in a separate Column 2. This extraction improves ion exchange efficiency by providing dedicated regeneration space while managing complexity through modular, standardized column designs.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The system uses hydraulic principles to circulate particles between columns and control fluid flow, leveraging natural pressure differentials and density-driven flow to reduce the need for complex mechanical pumping systems.

Inventive Principle:
Principle #29Pneumatics and hydraulics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The VA-LSCFB system achieves efficient continuous ion exchange with uninterrupted particle circulation and regeneration, reducing chemical consumption and dilution of process streams, while maintaining high ion exchange efficiency.

Implementation Method 1

a first fluid-feeding means to feed a first ion-containing fluid into a lower region of said first column to form a fluidized bed in the first column

Methodology Applied
Scientific EffectFluidization: Fluidisation

Implementation Method 2

continuous countercurrent ion exchange process for adsorbing ions of interest onto ion exchange particles from a feed liquor containing ions which when adsorbed on the particles cause the density of the particles to increase

Methodology Applied
Scientific EffectIon exchange: Ion Exchange

Implementation Method 3

said transport section comprising means to hydraulically move said particles upwardly into a liquid-solids separator

Methodology Applied
Scientific EffectHydraulic transport: Advection

Implementation Method 4

a transport section which connects to the upper region of the first column, said transport section comprising means to hydraulically move said particles upwardly into a liquid-solids separator to separate the particles from fluid

Methodology Applied
Scientific EffectCentrifugal separation: Centrifugal Separation

Data Source

PatentEP2704832B1Improved apparatus and circulating fluidized bed system
Publication Date: 2020.08.12 RENIX
  • EP2704832B1 patent drawingFigure 1
  • EP2704832B1 patent drawingFigure 2
  • EP2704832B1 patent drawingFigure 3

AI summary

A novel apparatus for an ion exchange system is provided. The apparatus comprises a first column for housing a first fluidized bed through which particles are flowed countercurrently to an ion-containing fluid to yield ion-loaded particles, a second column through which the ion-loaded particles are flowed countercurrently to an eluent fluid to yield regenerated particles, and a transport section which transfers the regenerated particles for re-introduction into the first column to repeat the ion exchange cycle in a continuous manner. A continuous method of ion exchange is also provided.