Clad Current Collector Interface Layer for Bipolar Solid-State Batteries
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Solution Overview
Problem
Bipolar solid-state batteries face issues with thick clad foil layers that have inferior mechanical bonding and a time-consuming, energy-inefficient fabrication process.
Innovation Solution
A clad current collector with a thermal interface layer comprising copper and aluminum foil layers bonded by a polyolefin adhesive and materials like pyrolytic graphite sheets and carbon nanotubes, enhancing thermal and electrical conductivity, and using a hot-rolling process for efficient production.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Strength
If thick clad foil current collectors are used, then mechanical strength is improved, but thermal and electrical conductivity deteriorate
Solution Approach 1:
The current collector uses a composite structure with copper foil providing electrical conductivity, aluminum foil providing mechanical strength, and a thermal interface layer with high thermal conductivity materials (pyrolytic graphite, carbon nanotubes) to enhance heat dissipation. This composite approach allows each layer to contribute its superior property, resolving the contradiction between mechanical strength and thermal/electrical conductivity.
Solution Approach 2:
Different regions of the current collector are assigned different materials optimized for their specific functions: copper for electrical conduction, aluminum for structural support, and thermally conductive materials at the thermal interface. This local optimization ensures that each part performs its designated function efficiently without compromising overall performance.
2Ease of manufacture
If conventional fabrication processes are used, then manufacturing simplicity is maintained, but energy consumption increases and production time lengthens
Solution Approach 1:
The thermal interface layer is pre-formed with thermally conductive materials before final assembly, allowing for optimized material distribution and reduced energy consumption during the bonding process. The polyolefin adhesive is applied in advance to ensure proper positioning and reduce rework, thereby decreasing overall production time and energy use.
3Stability of the object's composition
If conventional current collectors are used, then structural integrity is maintained, but mechanical bonding deteriorates
Solution Approach 1:
A thermal interface layer containing polyolefin adhesive is introduced as an intermediary between the copper and aluminum foil layers. This intermediate layer provides strong mechanical bonding between the dissimilar metals while maintaining the structural integrity of the overall current collector assembly.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The solution provides improved mechanical integrity, efficient heat dissipation, and reduced thickness, enabling cost-effective large-scale production of bipolar solid-state batteries.
Implementation Method 1
a thermal interface layer including adhesive and at least one material that increases thermal and electrical conductivity of the thermal interface layer
Implementation Method 2
A clad current collector includes a first foil layer, a second foil layer and a thermal interface layer including adhesive and at least one material that increases thermal and electrical conductivity
Data Source
AI summary
A battery cell includes a plurality of cathodes and a plurality of anodes. A plurality of solid electrolyte layers are arranged between first adjacent ones of the plurality of cathodes and the plurality of anodes. A plurality of clad current collectors are arranged between second adjacent ones of the plurality of cathodes and the plurality of anodes. The plurality of clad current collector includes a first foil layer, a second foil layer and a thermal interface layer including adhesive and at least one material that increases thermal and electrical conductivity of the thermal interface layer.


