Clad Copper Wire for Fuel Cell Current Collectors

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Solution Overview

Problem

Current collectors and wire interconnects in fuel cells face challenges in maintaining conductivity and environmental protection when exposed to varying environments, such as reducing and oxidizing gases, requiring multiple metal compositions that increase complexity and cost.

Innovation Solution

A current collector design featuring a high conductivity metal core with an environmentally isolating outer cladding, such as copper with Crofer 22 APU, allows for use in both oxidizing and reducing environments, reducing complexity and cost by eliminating the need for multiple materials.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If multiple metal compositions are used in different portions of the interconnect and current collector system, then environmental protection against varying conditions is improved, but device complexity increases

Engineering Contradiction:
Improveenvironmental protectionVSAvoiddevice complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies composite materials by creating a clad wire structure with a copper core and Crofer 22 APU alloy cladding. This composite structure combines the high electrical conductivity of copper with the environmental resistance of the ferritic stainless steel alloy, allowing a single wire to perform multiple functions that previously required different metal compositions in different locations.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The clad wire structure achieves universality by designing a single wire composition that can be utilized in a variety of different environments including both oxidizing and reducing conditions. This multi-functional wire eliminates the need for multiple specialized materials, reducing device complexity while maintaining environmental protection across all fuel cell components.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Reliability

If multiple metal compositions are used in different portions of the interconnect and current collector system, then environmental protection against varying conditions is improved, but manufacturing cost increases

Engineering Contradiction:
Improveenvironmental protectionVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The clad wire structure combines copper and Crofer 22 APU alloy in a single manufactured product, achieving environmental protection without requiring multiple separate materials. The composite structure is manufactured as an integrated component, simplifying the supply chain and reducing the costs associated with handling, installing, and maintaining multiple different metal compositions.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

By creating a universal wire composition that performs both electrical conduction and environmental protection functions across all fuel cell locations, the patent reduces manufacturing costs. This single wire type can be produced in volume and installed throughout the system, eliminating the need to manufacture and manage multiple specialized materials.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Device complexity

If a single wire composition is used throughout the system, then device complexity and manufacturing cost are reduced, but conductivity maintenance in varying environments deteriorates

Engineering Contradiction:
Improvedevice complexityVSAvoidconductivity maintenance
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The clad wire structure uses a copper core to maintain high electrical conductivity while the Crofer 22 APU alloy cladding provides environmental protection. This composite design allows the wire to maintain its conductivity function in varying environments without requiring multiple different wire compositions, thus reducing device complexity while preserving electrical performance.

Inventive Principle:
Principle #40Composite materials

4Ease of manufacture

If a single wire composition is used throughout the system, then manufacturing cost is reduced, but environmental protection against varying conditions deteriorates

Engineering Contradiction:
Improvemanufacturing costVSAvoidenvironmental protection
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The clad wire structure combines copper and Crofer 22 APU alloy to create a single wire composition that provides both electrical conductivity and environmental protection. This composite material approach maintains manufacturing simplicity while achieving the environmental resistance that would otherwise require multiple specialized materials, thus resolving the contradiction between manufacturing ease and environmental protection.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides improved conductivity and environmental protection, extending fuel cell operation endurance to nearly 1000 hours without significant degradation, as seen in the use of copper core with Crofer cladding, which maintains low resistivity and resistance to environmental conditions.

Implementation Method 1

at least one wire having an inner core of high conductivity metal

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 2

outer cladding of an environmentally isolating material

Methodology Applied
Scientific EffectOxidation resistance: Oxidation

Implementation Method 3

resistance to environmental conditions

Methodology Applied
Scientific EffectCorrosion resistance: Crevice Corrosion

Data Source

PatentUS7887975B2Clad copper wire having environmentally isolating alloy
Publication Date: 2011.02.15 REDWIRE DEFENSE TECH ENERGY SYSTEMS LLC
  • US7887975B2 patent drawing
  • US7887975B2 patent drawing
  • US7887975B2 patent drawing

AI summary

A current collector for a fuel cell that includes at least one wire having an inner core of high conductivity metal and an outer cladding of an environmentally isolating material. The current collector may be utilized in both an oxidizing and reducing environment.