Clarifying Agent Coloring Blend for Polypropylene Clarity

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Solution Overview

Problem

Conventional methods struggle to achieve adequate and homogeneous dispersion of additives at extremely low concentrations in polymers, particularly in the production of clear plastic articles, which affects their visual appearance and clarity when stacked or nested.

Innovation Solution

A composition comprising a clarifying agent and a water-insoluble coloring agent, with a ratio of 50-10,000 parts of coloring agent to 1 million parts of clarifying agent, is used to create a highly dispersed pigment in polypropylene, enhancing the visual clarity and appearance of plastic articles, even at low loadings of the coloring agent.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional mixing methods are used to disperse additives at extremely low concentrations, then the manufacturing process remains simple, but the dispersion homogeneity deteriorates

Engineering Contradiction:
Improvedispersion homogeneityVSAvoidmixing process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent applies preliminary action by pre-mixing the clarifying agent and coloring agent together to form a composite additive blend before adding it to the polymer. This pre-combination ensures that both agents are introduced simultaneously at the correct low concentrations, achieving homogeneous dispersion without requiring multiple sequential mixing steps. The pre-blended composite additive is then added in a single step to the polymer melt, resolving the contradiction between dispersion quality and process simplicity.

Inventive Principle:
Principle #10Preliminary action

2Manufacturing precision

If multiple let-down steps are used to achieve low additive concentrations, then the dispersion homogeneity improves, but the manufacturing time increases

Engineering Contradiction:
Improveadditive concentration precisionVSAvoidmanufacturing cycle time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The invention prepares the precise low-concentration additive blend in advance by combining the clarifying agent and coloring agent in specific ratios before polymer processing. This pre-prepared composite additive package eliminates the need for multiple let-down steps during production, as the correct concentration is achieved in a single addition step, thereby reducing manufacturing cycle time while maintaining precise concentration control.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent merges the clarifying agent and coloring agent into a single composite additive package that is added together in one step. This combination allows both agents to be dispersed simultaneously at their respective low concentrations, eliminating the need for separate let-down operations and reducing overall processing time while achieving the desired precision in additive concentration.

Inventive Principle:
Principle #5Merging (Combining)

3Ease of manufacture

If high colorant loading is used for adequate dispersion, then the manufacturing process is simple, but the visual clarity of stacked articles deteriorates

Engineering Contradiction:
Improvedispersion easeVSAvoidvisual clarity
Core Design Contradiction:
Ease of manufactureVSIllumination intensity

Solution Approach 1:

The patent changes the concentration parameter by using extremely low loadings of both clarifying agent (about 50-500 ppm) and coloring agent (about 5-50 ppm) in combination. This parameter change allows the coloring agent to provide sufficient color for single-article appearance while the clarifying agent maintains optical clarity. The key is that the agents work synergistically at low concentrations, and when stacked, the articles maintain better visual clarity compared to using high colorant loading alone.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite additive package combining the clarifying agent and coloring agent in specific ratios. This composite approach allows the two agents to work synergistically, where the clarifying agent enhances optical properties and the coloring agent provides color, both at low concentrations. The composite material approach enables adequate dispersion ease while maintaining visual clarity of stacked articles, as the combined effect is greater than the sum of individual agents at high concentrations.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The approach results in a high clarity polypropylene article with improved consumer appeal and appearance, as human subjects perceive the plastic as more clear and vivid, despite minimal reduction in measured haze values, indicating a significant visual benefit from the highly dispersed coloring agents.

Implementation Method 1

achieve adequate and homogenous dispersion of the additive in the polymer

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 2

the resulting batch may be mixed, followed by heat compounding to form a polymer

Methodology Applied
Scientific EffectMixing:

Implementation Method 3

heat compounding to form a polymer

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 4

heat compounding to form a polymer

Methodology Applied
Scientific EffectMelting: Melting

Data Source

PatentUS8232335B2Compositions and methods for making clarified aesthetically enhanced articles
Publication Date: 2012.07.31 MILLIKEN & CO
  • US8232335B2 patent drawing
  • US8232335B2 patent drawing
  • US8232335B2 patent drawing

AI summary

Thermoplastic articles may be manufactured having a high degree of visual appeal to consumers. Clarifying agents may be employed as additives in such thermoplastic articles to produce high clarity articles. A coloring agent may be mixed with clarifying agents to form a first blend, and then such a first blend may be applied in very low loadings to form a clarified polymeric article. It is possible to achieve an observable visual benefit while using very low loadings of coloring agent in a polyolefin, such as polypropylene. Carbon black is a pigment that may provide such observable benefits in polypropylene.