Clay-Free Drilling Fluid Additive Composition for High Temperature Resistance

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional whole-oil-based drilling fluids with organic clay additives suffer from poor temperature resistance and reservoir damage due to clay's inability to withstand high temperatures and its potential to contaminate oil and gas reservoirs.

Innovation Solution

A clay-free drilling fluid additive composition comprising a dimer acid-organic amine copolymer as a rheological modifier, modified polysiloxane nano-particles as a tackifier, and specific emulsifiers with a comb-like structure, which synergistically enhance suspending power and temperature resistance up to 220°C or higher.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If organic clay is added to whole-oil-based drilling fluid to improve suspending power, then suspending power is improved, but temperature resistance deteriorates

Engineering Contradiction:
Improvesuspending powerVSAvoidtemperature resistance
Core Design Contradiction:
Stability of the object's compositionVSTemperature

Solution Approach 1:

The invention removes organic clay from the drilling fluid system entirely. Instead of using organic clay to provide suspending power, the patent uses a combination of emulsifier, rheological modifier, and tackifier that work synergistically to achieve both suspending power and high temperature resistance without any clay components.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention creates a composite additive system consisting of emulsifier, rheological modifier, and tackifier that work together to provide multiple functions simultaneously. This composite approach replaces the single-component organic clay system, achieving both suspending power and temperature resistance through the synergistic interaction of multiple specialized components.

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If organic clay is added to whole-oil-based drilling fluid to improve suspending power, then suspending power is improved, but reservoir contamination occurs

Engineering Contradiction:
Improvesuspending powerVSAvoidreservoir contamination
Core Design Contradiction:
Stability of the object's compositionVSObject-generated harmful factors

Solution Approach 1:

The invention extracts and removes organic clay from the drilling fluid formulation. By eliminating clay entirely and replacing it with synthetic additives (emulsifier, rheological modifier, and tackifier), the system achieves suspending power without the harmful side effect of clay entering and damaging the reservoir.

Inventive Principle:
Principle #2Taking out (Extraction)

3Device complexity

If high oil-water ratio is used in whole-oil-based drilling fluid to maintain system simplicity, then system simplicity is maintained, but suspending power deteriorates

Engineering Contradiction:
Improvesystem simplicityVSAvoidsuspending power
Core Design Contradiction:
Device complexityVSStability of the object's composition

Solution Approach 1:

The invention makes each additive component perform multiple functions. The emulsifier not only maintains emulsion stability but also contributes to suspending power. The rheological modifier and tackifier work together to enhance both suspension capability and temperature resistance. This multi-functionality allows the system to maintain simplicity with high oil-water ratio while achieving good suspending power.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent uses a composite additive system where emulsifier, rheological modifier, and tackifier work synergistically. This composite approach enables the drilling fluid to achieve adequate suspending power with high oil-water ratio, eliminating the need for complex clay-based skeletal structures.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves desirable suspending power and high temperature resistance, preventing clay-related issues while maintaining drilling fluid stability and preventing reservoir contamination.

Implementation Method 1

the rheological modifier is a dimer acid-organic amine copolymer comprising structural units from dimer acid, structural units from alkylamine and structural units from arylamine

Methodology Applied
Scientific EffectRheological modification: Viscoelasticity

Implementation Method 2

the tackifier are modified polysiloxane nano-particles having a modifying Z group

Methodology Applied
Scientific EffectSurface modification: Adsorption

Implementation Method 3

the emulsifier is one or more of the compounds represented by the following Formula (1)

Methodology Applied
Scientific EffectEmulsification: Surfactant

Implementation Method 4

the clay-free whole-oil-based drilling fluid has a temperature resistance resisting a temperature of 220 °C or above

Methodology Applied
Scientific EffectThermal stability: Thermal Insulation

Data Source

PatentEP3202871B1Drilling fluid additive composition and high temperature resistant clay-free whole-oil-based drilling fluid
Publication Date: 2018.03.07 CHINA UNIV OF PETROLEUM (BEIJING)
  • EP3202871B1 patent drawingFigure 1
  • EP3202871B1 patent drawing
  • EP3202871B1 patent drawing

AI summary

The present invention relates to the field of petrochemical drilling and discloses a drilling fluid additive composition. The composition contains rheological modifier, emulsifier and tackifier. Among them, the rheological modifier is dimer acid-organic amine copolymer comprising structural units from dimer acid, structural units from alkylamine and structural units from arylamine; the tackifier is modified polysiloxane nano-particles, and the modifying group Z on the polysiloxane nano-particles is the emulsifier is one or more of the compounds represented by the following Formula (1). The present invention further provides a high temperature resistant clay-free whole-oil-based drilling fluid containing the foregoing composition. Through synergistic effect of the rheological modifier, the emulsifier and the tackifier in the composition, the present invention obtains a clay-free whole-oil-based drilling fluid with desirable suspending power and temperature resistance.