Clean-Then-Etch Process for Semiconductor Recess Regions

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Solution Overview

Problem

As semiconductor devices are scaled down, short channel effects lead to deteriorating operation characteristics, and existing methods fail to effectively remove etching objects without deforming underlying structures during the wet etch process.

Innovation Solution

A clean-then-etch process is employed, where a cleaning solution is used to fill recess regions and then a wet etch process is performed with a diluted etching solution, maintaining a lower concentration within the recess regions to prevent deformation of the underlying structure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If a wet etch process is performed to remove etching objects, then the etching objects are effectively removed, but the underlying structure in recess regions deforms due to excessive etching

Engineering Contradiction:
Improveetching object removal efficiencyVSAvoidrecess region structure integrity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent applies local quality by maintaining different etching solution concentrations in different regions: high concentration outside recess regions for effective etching object removal, and low concentration inside recess regions to prevent deformation of underlying structures. This spatial variation in etching aggressiveness resolves the contradiction between removal efficiency and structure preservation.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent introduces a cleaning solution as an intermediary substance that fills recess regions before the etch process. This cleaning solution acts as a protective mediator, diluting the etching solution concentration inside recess regions and preventing direct contact between high-concentration etching solution and the underlying structure, thereby preventing deformation while allowing effective etching outside.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If the etching solution concentration is increased to improve etching speed, then productivity increases, but deformation of the underlying structure worsens

Engineering Contradiction:
Improveetching speedVSAvoidstructure deformation
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent implements local quality by creating spatially varying etching solution concentrations: high concentration in non-recess areas for fast etching, and low concentration in recess areas for structure protection. This resolves the contradiction between etching speed and deformation prevention by optimizing concentration locally rather than uniformly.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent changes the concentration parameter of the etching solution based on location. By controlling the cleaning solution volume to achieve complete filling of recess regions, the system dynamically adjusts the effective etching solution concentration in recess areas versus non-recess areas, enabling high productivity without structure deformation.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If a cleaning process is performed before etching, then the substrate is cleaned, but additional process time is required

Engineering Contradiction:
Improveetching uniformityVSAvoidprocess cycle time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent merges the cleaning process and etching process into a single integrated operation. The cleaning solution is applied and simultaneously serves as a concentration-modifying agent during etching, eliminating the need for separate cleaning and etching steps. This resolves the contradiction between achieving cleaning benefits and maintaining process efficiency.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The cleaning solution performs multiple functions: it cleans the substrate surface and simultaneously acts as a concentration buffer in recess regions during etching. This multi-functionality eliminates redundant process steps and resolves the time loss contradiction while maintaining etching uniformity through concentration control.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method effectively removes etching objects outside recess regions while preventing or reducing etching and deformation of the inner parts of the recess regions, thereby improving the reliability of semiconductor devices.

Implementation Method 1

providing a cleaning solution to a whole surface of the substrate, the cleaning solution filling at least a portion of the recess region

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 2

a portion of the cleaning solution mixed with a portion of the etching solution introduced into the recess region during the wet etch process, thereby diluting the etching solution concentration within the recess region

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS9812332B2Etching methods and methods of manufacturing semiconductor devices using the same
Publication Date: 2017.11.07 SAMSUNG ELECTRONICS CO LTD
  • US9812332B2 patent drawing
  • US9812332B2 patent drawing
  • US9812332B2 patent drawing

AI summary

An etching method is disclosed. The etching method comprises providing on a substrate a structure comprising a recess region formed therein. The recess region includes an inner part and a mouth part whose width is less than that of the inner part. The etching method further comprises performing a clean-then-etch process to remove at least a portion of etching object formed outside the recess region. The performing a clean-then-etch process comprises performing a cleaning process to fill at least a portion of the recess region with a cleaning solution, and performing a wet etch process to the substrate in a state that the cleaning solution remains in the recess region.