Cleaning Composition Rapid Foam Collapse via Hansen Solubility

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Solution Overview

Problem

Current cleaning compositions for hard surfaces do not effectively balance foaming and foam collapse properties, which are associated with cleaning efficacy and rinse properties.

Innovation Solution

An aqueous cleaning composition comprising a surfactant, a water-immiscible compound with specific Hansen solubility parameters, and a water-miscible compound, which together provide improved foam formation and collapse properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If foaming is enhanced to indicate cleaning power, then cleaning efficacy is improved, but foam collapse becomes slower which worsens rinse properties

Engineering Contradiction:
Improvecleaning efficacyVSAvoidfoam collapse time
Core Design Contradiction:
ReliabilityVSDuration of action of moving object

Solution Approach 1:

The patent changes the chemical composition parameters of the cleaning formulation by incorporating specific compounds (e.g., citrus-based solvents, surfactants with balanced HLB values) that modify foam stability characteristics. This allows the foam to maintain sufficient stability for cleaning indication while incorporating ingredients that promote faster collapse after application, thus resolving the contradiction between cleaning efficacy and rinse properties.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite cleaning formulations that combine multiple ingredients with complementary properties - surfactants for foam generation, specific solvents for controlled foam stability, and rinse aids that accelerate foam collapse. This composite approach allows simultaneous optimization of both foam persistence for cleaning indication and rapid collapse for easy rinsing.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If foam stability is increased to signal cleaning power, then consumer perception of efficacy improves, but rinse performance deteriorates due to slower foam collapse

Engineering Contradiction:
Improveconsumer perception of efficacyVSAvoidrinse performance
Core Design Contradiction:
Ease of manufactureVSEase of operation

Solution Approach 1:

The foam in the cleaning composition is designed to exhibit periodic behavior - initially stable to provide visual confirmation of cleaning action, then transitioning to rapid collapse for easy rinsing. This time-dependent foam behavior creates a natural sequence where foam stability serves the cleaning indication function first, then automatically transitions to the rinse phase, resolving the contradiction between consumer perception and ease of operation.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent introduces specific intermediary compounds (such as citrus-derived solvents and foam modifiers) that act as mediators between the surfactant system and the foam structure. These intermediaries control the foam's lifecycle - maintaining it long enough for visual indication but facilitating its collapse for easy rinsing, thus bridging the gap between consumer perception and operational ease.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition generates desirable foam formation and collapse properties, enhancing cleaning efficacy and rinse performance.

Implementation Method 1

a surfactant; a first compound that is immiscible with water and has Hansen solubility parameters of 10 MPa0.5≤δD≤22 MPa0.5, 0≤δP≤14 MPa0.5, and 0≤δH≤14 MPa0.5

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 2

Consumers associate foaming of hard surface cleaners as being related to the efficiency and effectiveness of the cleaner

Methodology Applied
Scientific EffectFoam: Foam

Implementation Method 3

a first compound that is immiscible with water and has Hansen solubility parameters of 10 MPa0.5≤δD≤22 MPa0.5, 0≤δP≤14 MPa0.5, and 0≤δH≤14 MPa0.5, and a second compound that is miscible with water and has Hansen solubility parameters of 10 MPa0.5≤δD≤22 MPa0.5, 0≤δP≤10 MPa0.5, and 0≤δH≤14 MPa0.5

Methodology Applied
Scientific EffectHansen solubility parameters: Solvation

Data Source

PatentUS10138443B2Cleaning composition with rapid foam collapse
Publication Date: 2018.11.27 ROHM & HAAS CO
  • US10138443B2 patent drawing
  • US10138443B2 patent drawing
  • US10138443B2 patent drawing

AI summary

An aqueous cleaning composition including: a surfactant; a first compound that is immiscible with water and has Hansen solubility parameters of 10 MPa0.5≤δD≤22 MPa0.5, 0≤δP≤14 MPa0.5, and 0≤δH≤14 MPa0.5; and a second compound that is miscible with water and has Hansen solubility parameters of 10 MPa0.5≤δD≤22 MPa0.5, 0≤δP≤10 MPa0.5, and 0≤δH≤14 MPa0.5, wherein the surfactant, the first compound, and the second compound are each independently included in an amount of 0.01 to 30 weight percent, based on a total weight of the cleaning composition.