Clear Matt Coating Silane Treatment Matting Efficiency

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Solution Overview

Problem

Existing clear polymeric matte coatings using organic particles struggle to achieve high matting efficiency while maintaining a smooth, low-gloss finish, as spherical particles are less efficient than irregularly shaped inorganic particles and can result in undesirable film roughness.

Innovation Solution

A clear polymeric coating composition comprising 10-65% of a first polymer with a calculated Tg of -60°C to 100°C, 10-80% of a second particulate polymer with an average diameter of 0.5 microns to 30 microns, and 0.1-15% aminosilane, which improves matting efficiency and provides a low-gloss, smooth finish.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If spherical organic matting particles are used in the coating, then the coating can be formulated with organic particles, but the matting efficiency is reduced and film roughness increases

Engineering Contradiction:
Improveformulation with organic particlesVSAvoidmatting efficiency and film smoothness
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent changes the surface parameters of spherical organic particles by applying a silane treatment that creates nanoscale roughness on the particle surface. This surface modification transforms the particles from smooth spherical shapes with poor matting efficiency to particles with enhanced light-scattering capability, achieving matting efficiency comparable to irregular inorganic particles while maintaining the advantages of organic particles.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite structure by combining spherical organic particles with silane surface treatment. The core particle remains organic and spherical, while the surface layer provides the necessary roughness for effective matting. This composite approach allows the coating to benefit from both the formulation ease of organic particles and the matting efficiency typically associated with irregular inorganic particles.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If large particles and poly-disperse particle distributions are used, then matting efficiency increases, but macroscopic film roughness becomes undesirable

Engineering Contradiction:
Improvematting efficiencyVSAvoidmacroscopic film roughness
Core Design Contradiction:
Manufacturing precisionVSShape

Solution Approach 1:

The patent changes the surface parameters of the particles through silane treatment, creating nanoscale roughness that enhances light scattering. This allows the use of smaller, more monodisperse particles (0.5-30 microns) to achieve high matting efficiency without the need for large particle sizes or broad size distributions, thereby maintaining film smoothness.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent transitions the matting mechanism from relying on macroscopic particle size and shape variations to utilizing nanoscale surface features. By creating surface roughness at the nanometer scale through silane treatment, the particles achieve enhanced light-scattering capability without increasing their overall size or creating macroscopic film roughness.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating achieves enhanced matting efficiency and a soft-touch feel with reduced gloss and macroscopic film roughness, offering a more appealing finish compared to traditional organic particle-based coatings.

Implementation Method 1

Certain aminosilane compounds are effective in solving this problem... The coating achieves enhanced matting efficiency and a soft-touch feel with reduced gloss

Methodology Applied
Scientific EffectLight scattering: Scattering

Data Source

PatentEP2586836B1Clear matt coating
Publication Date: 2017.08.23 ROHM & HAAS CO
  • EP2586836B1 patent drawing

AI summary

A clear polymeric matte coating including from 10% to 65% by weight, based on the weight of the coating, of a first polymer having a calculated Tg of from -60°C to 100°C; from 10% to 80% by weight, based on the weight of the coating, of a second particulate polymer having an average particle diameter of from 0.5 microns to 30 microns; and from 0.1% to 15% by weight, based on the weight of the coating, of an aminosilane is provided. Also provided is an aqueous polymeric coating composition form which the clear matte coating may be formed and a method for improving the matting efficiency of an emulsion polymer having a calculated Tg of from -60°C to 150°C and an average particle diameter of from 0.5 microns to 30 microns in a coating.