Cleavable Multi-Alcohol Microcapsules for Aggressive Detergent Bases

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Solution Overview

Problem

The perfumery industry faces challenges with the rapid loss of olfactive benefit due to volatility of odoriferous compounds, particularly top-notes, and the instability of microcapsules in aggressive consumer product bases like surfactant detergents, necessitating improved stability and controlled release systems.

Innovation Solution

The development of core-shell microcapsules using cleavable multi-alcohols as building blocks, forming a polymeric wall through covalent adaptable networks, which provide stability and controlled release of hydrophobic ingredients.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If microcapsules are used to protect and control release of volatile compounds, then olfactive performance is improved, but stability in aggressive consumer product bases deteriorates

Engineering Contradiction:
Improveolfactive performanceVSAvoidstability in aggressive consumer product bases
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent employs composite wall materials comprising polyurea, polyurethane, or polyisocyanurate polymers combined with specific surfactants and stabilizers to create microcapsules that maintain structural integrity in aggressive consumer product bases while controlling the release of volatile compounds. The composite structure combines the protective encapsulation properties of polymeric walls with the stability-enhancing properties of surfactant-detergent combinations.

Inventive Principle:
Principle #40Composite materials

2Duration of action of moving object

If polyurea and polyurethane-based microcapsules are used, then long lasting olfactory effect is achieved, but stability in challenging bases with high surfactant levels deteriorates

Engineering Contradiction:
Improvelong lasting olfactory effectVSAvoidstability in challenging bases
Core Design Contradiction:
Duration of action of moving objectVSReliability

Solution Approach 1:

The patent modifies the chemical composition parameters of the microcapsule wall by incorporating specific ratios of polyisocyanates, polyols, surfactants, and stabilizers to adjust the wall's resistance to surfactant detergents while maintaining the controlled release properties necessary for long-lasting olfactory effects.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite wall structures combining polymeric materials (polyurea, polyurethane, polyisocyanurate) with surfactants and stabilizers to achieve both durability of scent release and stability in challenging bases containing high levels of aggressive surfactants.

Inventive Principle:
Principle #40Composite materials

3Productivity

If microcapsules are designed for controlled release, then release rate control is improved, but physical dissociation in challenging bases increases

Engineering Contradiction:
Improverelease rate controlVSAvoidphysical dissociation in challenging bases
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The patent applies different local properties to different parts of the microcapsule structure, with the polymeric wall providing mechanical strength and controlled release properties, while embedded surfactants and stabilizers provide localized protection against physical dissociation in surfactant-rich environments.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The microcapsules maintain stability in challenging bases and effectively deliver olfactive performance by encapsulating hydrophobic materials, such as perfumes, while ensuring controlled release.

Implementation Method 1

by providing new microcapsules based on cleavable multi-alcohols using covalent adaptable networks based on reversible reactions

Methodology Applied
Scientific EffectCovalent adaptable networks based on reversible reactions: Chemical Bonding

Implementation Method 2

adding at least one polyfunctional monomer in a hydrophobic material, preferably a perfume, to form an oil phase; preparing a dispersing phase, wherein the dispersing phase is not miscible with the oil phase

Methodology Applied
Scientific EffectPhase separation: Phase Change

Data Source

PatentUS20250304889A1Cleavable multi-alcohol-based microcapsules
Publication Date: 2025.10.02 FIRMENICH SA
  • US20250304889A1 patent drawing
  • US20250304889A1 patent drawing
  • US20250304889A1 patent drawing

AI summary

Described herein are cleavable multi-alcohol-based microcapsules. Also described herein are perfuming compositions and consumer products including such capsules, in particular perfumed consumer products in the form of home care or personal care products.