Conjugated Linoleic Acid Stabilizes TiO2 Sunscreen Viscosity

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Solution Overview

Problem

Cosmetic sunscreen compositions containing inorganic sunscreens, such as titanium dioxide, face challenges with stability issues like viscosity buildup and discoloration during extended storage, particularly in oil continuous emulsions.

Innovation Solution

A water-in-oil cosmetic composition incorporating 0.1 to 30% water-in-oil emulsifying silicone surfactant, 0.1 to 30% titanium dioxide sunscreen agent, and 0.1 to 3% conjugated linoleic acid, which imparts stability to the formulation by preventing significant changes in viscosity and color.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If inorganic sunscreen agents (titanium dioxide, zinc oxide) are used in oil continuous emulsions, then allergic reactions are minimized, but viscosity buildup and discoloration occur during extended storage

Engineering Contradiction:
Improveallergic reactionsVSAvoidviscosity and color stability
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

Conjugated linoleic acid serves as a stabilizing intermediary component in the emulsion formulation. It specifically interacts with inorganic sunscreen particles to prevent aggregation and maintain dispersion stability, thereby preventing viscosity buildup and discoloration during storage while allowing the use of safe inorganic sunscreen agents

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the chemical composition parameters of the emulsion by incorporating conjugated linoleic acid at specific concentrations (0.1-3%). This parameter change fundamentally alters the stability characteristics of the formulation, enabling long-term storage without degradation while maintaining the safety benefits of inorganic sunscreens

Inventive Principle:
Principle #35Parameter changes

2Reliability

If organic sunscreen agents are used, then effective UV protection is achieved, but adverse allergic reactions occur

Engineering Contradiction:
ImproveUV protection effectivenessVSAvoidallergic reactions
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The invention changes the active ingredient parameter from organic to inorganic sunscreen agents. This fundamental parameter change shifts the formulation from using effective but potentially allergenic organic compounds to using safe inorganic alternatives, while the conjugated linoleic acid ensures the inorganic formulation remains stable and effective

Inventive Principle:
Principle #35Parameter changes

3Duration of action of stationary object

If extended storage is required, then shelf life is improved, but viscosity buildup and discoloration worsen

Engineering Contradiction:
Improveshelf lifeVSAvoidviscosity and color stability
Core Design Contradiction:
Duration of action of stationary objectVSStability of the object's composition

Solution Approach 1:

Conjugated linoleic acid performs a preliminary protective action by stabilizing the emulsion formulation before storage begins. It proactively prevents the aggregation and degradation processes that would otherwise occur during extended storage, maintaining viscosity and color stability throughout the shelf life

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The conjugated linoleic acid acts as a mediating substance that maintains stability during extended storage periods. It continuously prevents interaction between inorganic sunscreen particles that would lead to aggregation and degradation, enabling the formulation to maintain its properties throughout the desired shelf life

Inventive Principle:
Principle #24Intermediary (Mediator)

Data Source

PatentEP1962784B1Cosmetic w/o emulsions with inorganic sunscreen stabilized with conjugated linoleic acid
Publication Date: 2009.11.11 UNILEVER PLC
  • EP1962784B1 patent drawing

AI summary

A cosmetic water-in-oil composition is provided which includes a water-in-oil emulsifying silicone surfactant, an ultrafine titanium dioxide and conjugated linoleic acid. The presence of conjugated linoleic acid stabilizes the composition against color degradation and also maintains an approximately steady viscosity.