CMC Environmental Barrier Coating via Segmented Slurry Infiltration

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Solution Overview

Problem

Ceramic matrix composite (CMC) materials used in high-temperature mechanical systems, such as gas turbine engines, face degradation due to reactions with environmental elements like water vapor, leading to reduced mechanical properties and lifetime, necessitating the development of effective environmental barrier coatings.

Innovation Solution

A method involving the application of a first slurry to infiltrate and dry a CMC substrate, followed by a second slurry application to form a denser outer surface layer with a composition of coarse and fine ceramic particles and diamond particles, which increases the solid content and durability of the CMC article, and subsequent machining to conform to dimensional tolerances without damaging the underlying substrate.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a CMC component is coated with an environmental barrier coating, then the resistance to environmental factors is improved, but the device complexity increases

Engineering Contradiction:
Improveresistance to environmental factorsVSAvoidcoating structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The coating is divided into multiple layers with distinct functions: a first layer containing fine ceramic particles for environmental barrier protection, and a second layer containing coarse ceramic particles and diamond for wear resistance and machining protection. This segmentation allows each layer to optimize its specific function while collectively providing comprehensive protection.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The coating uses composite material structures where ceramic particles are embedded in a matrix material, and diamond particles are incorporated into the second layer. This composite approach combines the chemical stability of ceramics with the hardness of diamond, achieving both environmental resistance and wear protection.

Inventive Principle:
Principle #40Composite materials

2Strength

If the surface layer is made denser with more solid content, then the durability and resistance to machining are improved, but the manufacturing complexity increases

Engineering Contradiction:
Improvedurability and resistance to machiningVSAvoidslurry application process complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The solid particles are segmented into different size categories (fine particles for the first layer, coarse particles for the second layer) and applied in sequential steps. This allows the surface layer to achieve high solid content and density while maintaining a manageable manufacturing process through staged application.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The slurry composition parameters are optimized by controlling the volume percentage of solid particles (40-70 vol.%), particle size distributions, and carrier material content. These parameter changes enable the formation of a dense, durable surface layer while keeping the manufacturing process feasible.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If the outer surface layer has high solid content, then the protection against environmental exposure is improved, but the manufacturing precision requirements increase

Engineering Contradiction:
Improveprotection against environmental exposureVSAvoiddimensional tolerance control
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The first slurry layer is applied and dried to establish a base coating with fine ceramic particles before applying the second slurry layer. This preliminary action creates a stable foundation that facilitates subsequent machining to precise dimensional tolerances while maintaining high environmental protection.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

Different regions of the coating have different properties: the first layer contains predominantly fine ceramic particles for environmental barrier function, while the second layer contains coarse particles and diamond for surface hardness. This local quality differentiation allows each region to optimize its specific function while achieving overall manufacturing precision.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enhances the durability and resistance of CMC articles to machining and environmental factors by forming a denser, more robust surface layer that reduces the risk of cracking and exposure of the reinforcement material, thereby extending the component's useful life.

Implementation Method 1

Drying the second slurry may comprise wicking the carrier material of the second slurry into at least some of the pores of the CMC substrate

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 2

drying the first slurry to form an infiltrated CMC; drying the second slurry to form an outer surface layer

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentEP3241817B1Forming a surface layer on a ceramic matrix composite article
Publication Date: 2021.01.27 ROLLS ROYCE HIGH TEMPERATURE COMPOSITES INC
  • EP3241817B1 patent drawingFigure 1~2
  • EP3241817B1 patent drawingFigure 3
  • EP3241817B1 patent drawingFigure 4

AI summary

The disclosure describes techniques for infiltrating a CMC substrate with a first slurry to at least partially fill at least some inner spaces of the CMC substrate, where the first slurry comprises first solid particles, drying the first slurry to form an infiltrated CMC including the first solid particles, depositing a second slurry including a carrier material and second solid particles on a surface of the infiltrated CMC, where the second solid particles comprise a plurality of fine ceramic particles, a plurality of coarse ceramic particles, and a plurality of diamond particles, drying the second slurry to form an article having an outer surface layer comprising the second solid particles on the infiltrated CMC, and infiltrating the article with a molten infiltrant to form a composite article.