Ceramic Matrix Composite Fiber Concentration Gradient

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Solution Overview

Problem

Ceramic matrix composites (CMCs) exhibit significant porosity, particularly in the center, due to uneven precursor infiltration, leading to density variations and reduced oxidation resistance, which affects their in-plane and inter-laminar properties.

Innovation Solution

A ceramic matrix composite laminate with a gradient in fiber concentration per unit volume from the outermost layer to the interior, where the distance between fibers varies, facilitating uniform precursor infiltration and reducing porosity, achieved by stacking layers with different fiber concentrations and spacings.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If uniform fiber concentration is used throughout the preform, then manufacturing is simpler, but porosity increases significantly in the center reducing oxidation resistance

Engineering Contradiction:
Improvepreform manufacturing simplicityVSAvoidoxidation resistance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent applies local quality by varying the fiber concentration in different regions of the preform. The outer layers have higher fiber concentration to promote precursor infiltration and form dense, oxidation-resistant matrix, while the center has lower fiber concentration to facilitate precursor access. This spatial variation in fiber concentration locally optimizes each region's properties for its specific functional requirements.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent implements parameter changes by systematically varying the fiber concentration parameter through the thickness of the preform. By controlling the fiber concentration to decrease from outer layers toward the center, the patent creates gradient conditions that fundamentally change the infiltration behavior and final matrix density distribution, resolving the contradiction between manufacturing simplicity and oxidation resistance.

Inventive Principle:
Principle #35Parameter changes

2Strength

If preform thickness is increased to improve structural capacity, then load-bearing capability increases, but porosity increases in the center affecting mechanical properties

Engineering Contradiction:
Improvestructural load-bearing capabilityVSAvoidmatrix density uniformity
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The patent applies local quality by varying the fiber concentration in different regions of the preform. The outer layers have higher fiber concentration to promote precursor infiltration and form dense, oxidation-resistant matrix, while the center has lower fiber concentration to facilitate precursor access. This spatial variation in fiber concentration locally optimizes each region's properties for its specific functional requirements.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent implements parameter changes by systematically varying the fiber concentration parameter through the thickness of the preform. By controlling the fiber concentration to decrease from outer layers toward the center, the patent creates gradient conditions that fundamentally change the infiltration behavior and final matrix density distribution, resolving the contradiction between manufacturing simplicity and oxidation resistance.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If fiber concentration is increased to reduce porosity, then oxidation resistance improves, but precursor infiltration becomes uneven and center regions remain porous

Engineering Contradiction:
Improveoxidation resistanceVSAvoidmatrix density uniformity
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent applies local quality by varying the fiber concentration in different regions of the preform. The outer layers have higher fiber concentration to promote precursor infiltration and form dense, oxidation-resistant matrix, while the center has lower fiber concentration to facilitate precursor access. This spatial variation in fiber concentration locally optimizes each region's properties for its specific functional requirements.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent implements parameter changes by systematically varying the fiber concentration parameter through the thickness of the preform. By controlling the fiber concentration to decrease from outer layers toward the center, the patent creates gradient conditions that fundamentally change the infiltration behavior and final matrix density distribution, resolving the contradiction between manufacturing simplicity and oxidation resistance.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in a more uniform matrix density throughout the composite, enhancing its mechanical properties and oxidation resistance by ensuring complete precursor infiltration and minimizing pore formation.

Implementation Method 1

Within the reaction chamber at an elevated temperature, the preform can be exposed to certain precursors. On being exposed to these precursors at an elevated temperature, a reaction can occur resulting in the deposition of a ceramic on the fibers of the preform to form a ceramic matrix composite.

Methodology Applied
Scientific EffectChemical vapor infiltration: Chemical Vapour Deposition

Implementation Method 2

The porosity can increase with thickness and can significantly impact both the in-plane and inter-laminar properties and overall oxidation resistance of the composite.

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS20240278543A1Ceramic matrix composites and method of making
Publication Date: 2024.08.22 RTX CORP
  • US20240278543A1 patent drawing
  • US20240278543A1 patent drawing
  • US20240278543A1 patent drawing

AI summary

A ceramic matrix composite laminate comprises a ceramic matrix that encapsulates a plurality of layers. Each layer comprises fibers. Each layer comprises a plurality of fill fibers and a plurality of warp fibers or a plurality of bias fibers. The outermost layer contains a different concentration of fibers per unit volume than a layer located near an interior of the ceramic matrix composite laminate. A gradient in the number of fibers exists between the outermost layer and the layer located at the interior of the ceramic matrix composite laminate, or a combination thereof. A combined ceramic matrix composite comprises a plurality of composite laminates; wherein each laminate has a different fiber concentration gradient from another laminate that it is in contact with.