Carboxymethyl Cellulose Particle Hydration for Detergent Solubility

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Carboxymethyl cellulose particles in solid laundry detergents tend to form gels when in close proximity, leading to poor dissolution profiles, especially in cold wash water conditions, and large particles result in poor dissolution performance.

Innovation Solution

A solid laundry detergent composition with carboxymethyl cellulose particles pre-hydrated with a controlled amount of water and low levels of electrolytes, combined with a bimodal molecular weight distribution and hydrophobic modifications, to prevent surface gelling and enhance solubility.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If small particles of carboxymethyl cellulose are used, then dissolution performance is improved, but the composition becomes very prone to gelling

Engineering Contradiction:
Improvedissolution performanceVSAvoidgelling tendency
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The patent applies parameter changes by carefully controlling the particle size of carboxymethyl cellulose within a specific range (5-50 micrometers) and controlling the water content (5-20% w/w) and electrolyte levels (0.1-5% w/w) to optimize dissolution performance while preventing gelling. This resolves the contradiction by finding the optimal parameter window where both fast dissolution and gel-free composition are achieved.

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If carboxymethyl cellulose particles are pre-hydrated with controlled water, then surface gelling is reduced, but dissolution performance must be maintained

Engineering Contradiction:
Improvesurface gelling reductionVSAvoiddissolution performance
Core Design Contradiction:
Stability of the object's compositionVSProductivity

Solution Approach 1:

The patent applies preliminary action by pre-hydrating the carboxymethyl cellulose particles with a controlled amount of water (5-20% w/w) before incorporation into the detergent composition. This pre-hydration modifies the particle surface properties to reduce sticky gel formation during subsequent water contact, while the controlled water level ensures dissolution performance is maintained.

Inventive Principle:
Principle #10Preliminary action

3Stability of the object's composition

If electrolytes are removed or controlled to very low levels, then surface gelling is impeded, but formulation flexibility is reduced

Engineering Contradiction:
Improvesurface gelling preventionVSAvoidformulation flexibility
Core Design Contradiction:
Stability of the object's compositionVSAdaptability or versatility

Solution Approach 1:

The patent applies parameter changes by controlling electrolyte levels within a specific range (0.1-5% w/w) rather than complete removal. This controlled reduction in electrolytes prevents surface gelling by reducing ionic strength effects that promote gelation, while still allowing sufficient formulation flexibility for creating effective laundry detergent compositions.

Inventive Principle:
Principle #35Parameter changes

4Stability of the object's composition

If large carboxymethyl cellulose particles are used, then gelling is reduced, but dissolution performance becomes very poor

Engineering Contradiction:
Improvegelling tendencyVSAvoiddissolution performance
Core Design Contradiction:
Stability of the object's compositionVSProductivity

Solution Approach 1:

The patent applies parameter changes by optimizing the particle size to a specific intermediate range (5-50 micrometers). This size is large enough to reduce surface area and minimize gel formation, yet small enough to maintain good dissolution performance. The optimal particle size balances both requirements by avoiding the extremes of very small (prone to gelling) and very large (poor dissolution) particles.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves improved dissolution performance and solubility, minimizing water-insoluble residues and maintaining a good environmental profile by controlling particle size and electrolyte levels.

Implementation Method 1

The carboxymethyl cellulose particle comprises: (i) from 70wt% to 98wt% carboxymethyl cellulose having an average degree of carboxymethyl substitution of from 0.6 to 0.9; (ii) from 2wt% to 12wt% water

Methodology Applied
Scientific EffectSolvation: Solvation

Implementation Method 2

with hydrophobic modifications, to prevent surface gelling and enhance solubility

Methodology Applied
Scientific EffectHydrophobe: Hydrophobe

Data Source

PatentEP2302025B1A laundry detergent composition comprising a highly water-soluble carboxmethyl cellulose particle
Publication Date: 2016.04.13 PROCTER & GAMBLE CO
  • EP2302025B1 patent drawing
  • EP2302025B1 patent drawing
  • EP2302025B1 patent drawing

AI summary

The present invention relates to a solid laundry detergent composition comprising: (a) detersive surfactant; and (b) from 0.05wt% to 20wt% carboxymethyl cellulose particle, wherein the carboxymethyl cellulose particle comprises: (i) from 70wt% to 98wt% carboxymethyl cellulose having an average degree of carboxymethyl substitution of from 0.6 to 0.9; (ii) from 2wt% to 12wt% water; (iii) optionally from 0wt% to 4wt% sodium glycolate; and (iv) optionally from 0wt% to 4wt% sodium chloride.