CMP System O3/DIW Buffing for Residue Removal

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Solution Overview

Problem

The semiconductor industry faces challenges in achieving effective planarization and cleaning of metal gate structures during the fabrication of advanced ICs, particularly due to residue corrosion inhibitors and metal residues left after chemical mechanical polishing (CMP) processes, which can lead to interfacial adhesion issues and metal corrosion.

Innovation Solution

A CMP system incorporating an ozone (O3) and deionized water (DIW) solution is used for buffing and cleaning, which reacts with residue corrosion inhibitors and metal residues, forming a stable aluminum oxide layer to improve interfacial adhesion and prevent corrosion, while also using megasonic cleaning and brushing to ensure thorough removal of contaminants.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If chemical mechanical polishing (CMP) is used for planarization, then wafer planarity is improved, but residue corrosion inhibitors and metal residues remain on the surface causing adhesion issues and corrosion

Engineering Contradiction:
Improvewafer planarityVSAvoidresidue corrosion inhibitors and metal residues
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The patent extracts and removes the harmful residues (corrosion inhibitors and metal residues) left by CMP processing through a dedicated cleaning process using ozone/demineralized water solution, separating the planarization function from the residue removal function

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent introduces an intermediary cleaning process using ozone/demineralized water solution between the CMP step and subsequent processing steps to eliminate harmful residues without affecting the planarity achieved by CMP

Inventive Principle:
Principle #24Intermediary (Mediator)

2Object-generated harmful factors

If conventional cleaning methods are used after CMP, then some residues are removed, but interfacial adhesion issues and metal corrosion persist

Engineering Contradiction:
Improveresidue removalVSAvoidinterfacial adhesion and metal corrosion resistance
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent employs ozone, a strong oxidant, to effectively remove organic residue corrosion inhibitors and convert metal residues into stable oxide forms that do not cause adhesion issues or corrosion, thereby improving both cleanliness and reliability

Inventive Principle:
Principle #38Strong oxidants (Accelerated oxidation)

Solution Approach 2:

The patent converts the harmful metal residues into beneficial stable oxide layers through oxidation, transforming the corrosion risk into a protective layer that actually improves interfacial adhesion and prevents further corrosion

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Reliability

If thorough cleaning is performed to remove all residues, then adhesion and corrosion resistance improve, but processing time and complexity increase

Engineering Contradiction:
Improveinterfacial adhesion and corrosion resistanceVSAvoidprocessing complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent creates a multi-functional cleaning process that simultaneously removes organic residues, converts metal residues to stable oxides, and prepares the surface for optimal adhesion in a single integrated step, reducing overall processing complexity

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent changes the chemical parameters of the cleaning solution by using ozone-demineralized water with specific pH and concentration ranges to achieve multiple cleaning objectives under optimized conditions, simplifying the process while maintaining high reliability

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The O3/DIW solution effectively removes organic residues and forms a thicker, more dense aluminum oxide layer, enhancing interfacial adhesion and preventing metal corrosion, thereby improving the reliability and performance of subsequent film deposition and etching processes.

Implementation Method 1

ozone (O3) and deionized water (DIW) solution is used for buffing and cleaning, which reacts with residue corrosion inhibitors and metal residues, forming a stable aluminum oxide layer

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

using megasonic cleaning and brushing to ensure thorough removal of contaminants

Methodology Applied
Scientific EffectUltrasonic vibration: Ultrasonic Vibration

Data Source

PatentUS10755934B2Systems and methods for chemical mechanical polish and clean
Publication Date: 2020.08.25 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US10755934B2 patent drawing
  • US10755934B2 patent drawing
  • US10755934B2 patent drawing

AI summary

A chemical mechanical polishing (CMP) system and associated semiconductor fabrication methods are disclosed herein. An exemplary method includes performing a planarization process in a polishing unit of a CMP system to planarize a surface of a material layer using a CMP slurry. The method further includes, after performing the planarization process, performing a buffing process in the polishing unit of the CMP system to buff the surface of the material layer using an ozone gas dissolved in deionized water (O3/DIW) solution. The method further includes controlling the performing of the planarization process and the performing of the buffing process, such that the CMP slurry is received by the polishing unit from a first pipeline during the planarization process and the O3/DIW solution is received by the polishing unit from a second pipeline during the buffing process.