CMP Slurry Composition for Oxide Selectivity and Dishing Control

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Solution Overview

Problem

The challenge in semiconductor manufacturing is to achieve a high polishing rate for insulating films while inhibiting the polishing of polysilicon films, maintaining selectivity, and preventing dishing during the CMP process.

Innovation Solution

A polishing slurry composition comprising a non-ionic macromolecule polymer with at least one amide bond, a selectivity control agent, and abrasive particles, which together provide a high polishing rate for insulating films, inhibit polysilicon film polishing, and offer a polishing stop function to prevent dishing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If polishing selectivity for insulating film is increased, then polishing rate of insulating film is improved, but dishing occurs in the insulating film

Engineering Contradiction:
Improvepolishing rate of insulating filmVSAvoidsurface flatness of insulating film
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent modifies the chemical composition parameters of the polishing slurry by incorporating specific organic acids (benzoic acid, phenylacetic acid, naphthoic acid, mandelic acid, or picolinic acid) at controlled concentrations (0.01-5 wt%). This chemical parameter change enables the slurry to achieve high polishing rates for insulating films while simultaneously controlling dishing through the selective chemical interaction of these acids with different film materials during the CMP process.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If polishing selectivity is increased to protect polysilicon film, then polysilicon film loss is reduced, but insulating film may be excessively polished leading to dishing

Engineering Contradiction:
Improvepolysilicon film protectionVSAvoidinsulating film surface flatness
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent introduces organic acids as intermediary substances that mediate between the abrasive particles and the film materials. These organic acids selectively interact with the insulating film and polysilicon film through chemical mechanisms, enabling the abrasive particles to remove insulating film efficiently while automatically reducing their effectiveness on polysilicon film, thus providing both high selectivity and dishing control without requiring extreme polishing parameter adjustments.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition effectively reduces polysilicon film loss during excessive polishing, minimizes dishing in insulating films, and achieves high planarization enhancement, thereby enhancing the reliability and characteristics of semiconductor devices.

Implementation Method 1

a non-ionic (macromolecule) polymer having at least one amide bond

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

a selectivity control agent

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 3

abrasive particles

Methodology Applied
Scientific EffectAbrasion: Abrasion

Data Source

PatentUS12247141B2Polishing slurry composition
Publication Date: 2025.03.11 KC TECH CO LTD
  • US12247141B2 patent drawing
  • US12247141B2 patent drawing
  • US12247141B2 patent drawing

AI summary

The present invention relates to a polishing slurry composition. A polishing slurry composition according to an embodiment of the present disclosure comprises: a nonionic polymer having at least one amide bond; a selectivity control agent; and abrasive particles.