Carbon Nanotube Bolometer Film Structure and Dip-Coating

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Solution Overview

Problem

Existing bolometers with carbon nanotube films formed by printing techniques face challenges in reducing resistance, as it is difficult to achieve optimal electrical connectivity between the film and electrodes.

Innovation Solution

A bolometer design featuring a base material with a stacking surface, two electrodes, and a film containing carbon nanotubes, where the film includes a first portion stacked on the electrode surface, a second portion stacked between the electrodes, and a connection portion connecting these portions on the side surface, with an average film thickness of the second portion less than 10 nm. The manufacturing method involves immersing the base material in a dispersion liquid containing carbon nanotubes and pulling it up at a controlled speed to achieve oriented carbon nanotube layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a film made of carbon nanotubes is formed by using a printing technique, then the film can be manufactured with existing techniques, but it is difficult to reduce the resistance of the bolometer

Engineering Contradiction:
Improvemanufacturing techniqueVSAvoidresistance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent changes the film thickness parameter to less than 10 nm (ultra-thin) and controls the pulling speed parameter during manufacturing to achieve optimal resistance values while maintaining manufacturability through dip-coating technique

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces a three-dimensional film structure with specific thickness dimension (less than 10 nm) and spatial orientation (stacked on substrate with connection portion on side surface) to achieve low resistance while using dip-coating manufacturing

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Reliability

If the film thickness is reduced to less than 10 nm, then the resistance is reduced, but the manufacturing precision required increases

Engineering Contradiction:
ImproveresistanceVSAvoidfilm thickness control
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The dip-coating process allows the film thickness to be self-regulated by the capillary action and adsorption characteristics of carbon nanotubes on the substrate, achieving uniform ultra-thin films (less than 10 nm) without requiring complex precision control equipment

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent uses liquid-phase dip-coating where the dispersion liquid penetrates and forms the carbon nanotube film through capillary action and surface tension effects, enabling precise thickness control at the nanometer scale through simple immersion and withdrawal motion

Inventive Principle:
Principle #29Pneumatics and hydraulics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration allows for easy reduction in resistance by forming conductive paths through the electrical connection of carbon nanotubes between the film and electrodes, while maintaining a high temperature coefficient of resistance (TCR) by controlling the thickness and orientation of the carbon nanotube layers.

Implementation Method 1

a film that contains carbon nanotubes, in which the film includes a first portion that is stacked on the main surface, a second portion that is stacked on the stacking surface between the two electrodes, and a connection portion that connects the first portion and the second portion and is provided on the side surface

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 2

immersing the base material in a dispersion liquid containing carbon nanotubes, and pulling up the immersed base material at a moving speed of 0.3 μm/s or less such that the stacking surface passes through a liquid surface of the dispersion liquid

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS20250067601A1Bolometer and manufacturing method
Publication Date: 2025.02.27 NEC CORP
  • US20250067601A1 patent drawing
  • US20250067601A1 patent drawing
  • US20250067601A1 patent drawing

AI summary

A bolometer includes a base material that has a stacking surface, two electrodes each of which has a main surface and a side surface extending from the main surface to the stacking surface, and a film that contains carbon nanotubes, in which the film includes a first portion that is stacked on the main surface, a second portion that is stacked on the stacking surface between the two electrodes, and a connection portion that connects the first portion and the second portion and provided on the side surface, and in which an average film thickness of the second portion is less than 10 nm.