Carbon Nanotube Catalyst Composition for Conductivity and Dispersibility

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Solution Overview

Problem

Conventional carbon nanotubes have poor solubility and dispersibility, making them unsuitable as conductive materials for high-capacity secondary batteries, despite their excellent electrical conductivity.

Innovation Solution

A catalyst comprising a metal component represented by Chemical Formula 1 (Cox:[M1,Zr]y:M2z) is used to synthesize carbon nanotubes with improved electrical conductivity and dispersibility, where Co represents cobalt or its oxides, M1 includes metals like Al, Ca, Si, or Mg, Zr is zirconium, and M2 includes metals like W, V, or Mo, with specific mole ratios optimizing the growth and properties of carbon nanotubes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional carbon nanotubes are used as conductive materials, then electrical conductivity is excellent, but solubility and dispersibility are poor

Engineering Contradiction:
Improveelectrical conductivityVSAvoiddispersibility
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The invention changes the chemical composition parameters of the catalyst system by introducing a specific four-component metal catalyst system (Co, Al, Zr, V) with controlled ratios. This modifies the growth conditions and structural parameters of carbon nanotubes, resulting in products with improved dispersibility while maintaining electrical conductivity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite catalyst system combining four different metal components (Co, Al, Zr, V) rather than a single metal catalyst. This composite approach allows synergistic effects that produce carbon nanotubes with optimized properties for both conductivity and dispersibility

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If physical post-processing methods are used to improve dispersibility, then dispersibility is enhanced, but work difficulties and costs increase

Engineering Contradiction:
ImprovedispersibilityVSAvoidmanufacturing complexity
Core Design Contradiction:
Ease of operationVSEase of manufacture

Solution Approach 1:

The invention performs the dispersibility enhancement action during the carbon nanotube synthesis process itself, rather than as a subsequent post-processing step. The catalyst system is designed to produce nanotubes with inherent dispersibility characteristics, eliminating the need for additional mechanical processing steps

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention extracts the dispersibility improvement function from the post-processing stage and integrates it into the synthesis stage. By incorporating specific metal components (Al, Zr) into the catalyst system, the dispersibility property is built-in during manufacturing rather than added later

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The catalyst enables the production of carbon nanotubes with excellent electrical conductivity and dispersibility, enhancing the capacity and lifespan of secondary batteries when used as conductive materials.

Implementation Method 1

A catalyst comprising a metal component represented by Chemical Formula 1 (Cox:[M1,Zr]y:M2z) is used to synthesize carbon nanotubes with improved electrical conductivity and dispersibility

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentUS20240408583A1Catalyst for manufacturing carbon nanotubes and carbon nanotube aggregate manufactured using the same
Publication Date: 2024.12.12 KOREA KUMHO PETROCHEMICAL CO LTD
  • US20240408583A1 patent drawing

AI summary

One embodiment of the present disclosure provides a catalyst for manufacturing carbon nanotubes, including a metal component represented by the following Chemical Formula 1:Cox:[M1,Zr]y:M2z  [Chemical Formula 1]wherein Co represents cobalt or oxides or derivatives thereof, M1 represents at least one metal, or oxides or derivatives thereof, selected from Al, Ca, Si, Ti, and Mg, Zr represents zirconium, or oxides or derivatives thereof, M2 represents at least one metal, or oxides or derivatives thereof, selected from W, V, Mn, and Mo, x/y satisfies 0.2≤x/y≤2.6, and x/z satisfies 6≤x/z≤13.