Carbon Nanotube Dispersion for Low-Viscosity Electrode Slurries

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Solution Overview

Problem

Carbon nanotubes face issues with low dispersibility and aggregation due to strong van der Waals attraction, leading to increased viscosity over time, which complicates their use in high-density electrode manufacturing for lithium secondary batteries.

Innovation Solution

A carbon nanotube dispersion is prepared using a dispersant containing an N atom and a compound with a sulfonic acid group, a hydroxyl group, and an aromatic ring, in a specific weight ratio, to enhance dispersibility and maintain low viscosity over time.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If mechanical dispersion treatment such as ultrasonic treatment is used to disperse carbon nanotubes, then dispersibility is improved, but carbon nanotubes aggregate again after treatment and viscosity increases over time

Engineering Contradiction:
ImprovedispersibilityVSAvoidviscosity stability
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The patent introduces a dispersant as an intermediary substance between carbon nanotubes and the dispersion medium. The dispersant molecules adsorb onto the carbon nanotube surface through van der Waals forces and π-π interactions, creating a steric barrier that prevents aggregation. This mediator maintains stable dispersion and controls viscosity over time without requiring continuous mechanical energy input.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent optimizes the molecular weight and chemical structure parameters of the dispersant to achieve optimal performance. By selecting dispersants with specific molecular weight ranges and functional groups, the system achieves balanced dispersibility and viscosity stability, transforming the physical-chemical parameters of the dispersion system to resolve the contradiction between initial dispersion quality and long-term stability.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If carbon nanotubes are used as conductive material in electrodes, then electrical conductivity is improved, but dispersibility deteriorates due to strong van der Waals attraction

Engineering Contradiction:
Improveelectrical conductivityVSAvoiddispersibility
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The dispersant acts as a mediator that bridges carbon nanotubes and the dispersion medium. It adsorbs onto the nanotube surface through van der Waals forces and π-π interactions between the dispersant's aromatic rings and the carbon nanotube graphitic structure, providing steric stabilization while maintaining the electrical conductivity of the nanotubes. This allows simultaneous achievement of good dispersibility and electrical conductivity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite system consisting of carbon nanotubes, dispersant, and dispersion medium. The dispersant forms a composite structure around the nanotubes, creating a stable colloidal system that combines the high conductivity of pure carbon nanotubes with the dispersibility provided by the dispersant molecules, thus achieving both properties simultaneously.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The dispersion exhibits excellent dispersibility and low viscosity, allowing uniform distribution of carbon nanotubes in electrodes, reducing resistance and improving electrode performance.

Implementation Method 1

carbon nanotubes have problems of low dispersibility and arising aggregation phenomenon due to strong van der Waals attraction between carbon nanotubes

Methodology Applied
Scientific EffectVan der Waals attraction: Van der Waals Force

Implementation Method 2

the dispersant comprises a first dispersant and a second dispersant... the first dispersant is a dispersant comprising an N atom, the second dispersant is a compound comprising a sulfonic acid group, a hydroxyl group and an aromatic ring

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS20260084965A1Carbon nanotube dispersion and method for preparing the same
Publication Date: 2026.03.26 LG CHEM LTD

AI summary

The present invention relates to a carbon nanotube dispersion comprising carbon nanotubes, a dispersant and a dispersion medium, wherein the dispersant comprises a first dispersant and a second dispersant in a weight ratio of 100:10 to 100:90, the first dispersant is a dispersant comprising an N atom, the second dispersant is a compound comprising a sulfonic acid group, a hydroxyl group and an aromatic ring in a molecular structure, and a weight ratio of the carbon nanotubes and the dispersant is 100:50 to 100:500, thereby having low viscosity and a little change in viscosity over time.