CNT Electron Emission Source Vertical Alignment via Taping

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Solution Overview

Problem

Existing methods for manufacturing carbon nanotube (CNT) electron emission sources face challenges such as weak adhesion between CNTs and the cathode substrate, difficulty in controlling density and uniformity, and complexity in manufacturing large-scale sources, which affect reliability and stability.

Innovation Solution

A method involving a plate-shaped cathode with a needle-shaped electron emission material layer, an adhesive layer for fixation, and a fixing element to secure the cathode to a base, allowing for easy formation and transfer of a CNT layer using a suspension filtering process and taping to erect the CNTs vertically, enhancing adhesion and uniformity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Shape

If CNTs are vertically grown directly on a conductor through decomposition of carbon source gas at high temperature, then the CNTs can be aligned vertically with controlled diameter and length, but the adhesion between CNTs and cathode substrate is weak and it is difficult to manufacture large sources

Engineering Contradiction:
Improvevertical alignment of CNTsVSAvoidadhesion between CNTs and cathode substrate
Core Design Contradiction:
ShapeVSReliability

Solution Approach 1:

The patent applies preliminary action by depositing a catalytic metal layer and forming a CNT layer on the cathode substrate before the actual electron emission operation. This preliminary formation of the CNT layer through suspension coating and drying ensures strong adhesion from the beginning, avoiding the weak adhesion problem of direct high-temperature growth. The CNTs are then vertically aligned through a taping process that erects them perpendicular to the substrate surface.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses an intermediary approach by introducing a catalytic metal layer (such as iron, cobalt, or nickel) as a mediator between the cathode substrate and the CNTs. This catalytic layer facilitates CNT growth and enhances adhesion. Additionally, a suspension containing CNTs and a binder is used as an intermediary medium to transfer CNTs to the substrate, ensuring strong bonding without requiring high-temperature direct growth.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If CNT powder is attached to cathode through suspension filtering or other methods, then adhesion can be improved, but it is difficult to control density and uniformity of the CNT layer

Engineering Contradiction:
Improveadhesion between CNTs and cathode substrateVSAvoiduniformity and density control of CNT layer
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies parameter changes by carefully controlling the concentration of CNTs in the suspension, the drying temperature, and the taping force. By adjusting these parameters, the density and uniformity of the CNT layer can be precisely controlled. The suspension concentration is optimized to achieve the desired CNT density, while the drying process parameters are tuned to ensure uniform distribution without aggregation.

Inventive Principle:
Principle #35Parameter changes

3Area of stationary object

If conventional methods are used to manufacture large CNT field electron emission sources, then scale can be increased, but manufacturing complexity and process difficulty increase significantly

Engineering Contradiction:
Improvesize of electron emission sourceVSAvoidmanufacturing process complexity
Core Design Contradiction:
Area of stationary objectVSDevice complexity

Solution Approach 1:

The patent applies segmentation by dividing the manufacturing process into distinct, manageable steps: (1) preparing the cathode substrate with catalytic metal layer, (2) coating the CNT suspension, (3) drying to form CNT layer, and (4) taping to vertically align CNTs. This segmented approach allows each step to be optimized independently and facilitates large-scale production by enabling parallel processing and automation of individual steps.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in a reliable, stable, and cost-effective electron emission source with improved uniformity and reproducibility, capable of large-scale production without the need for high-temperature processes or organic materials that could interfere with electron emission.

Implementation Method 1

an adhesive layer for fixing the electron emission material layer to a conductive plate-shaped cathode

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

a fixing element fixing the cathode to a base

Methodology Applied
Scientific EffectMechanical fixation: Mechanical Fastener

Implementation Method 3

easy formation and transfer of a CNT layer using a suspension filtering process

Methodology Applied
Scientific EffectSuspension filtering: Filter (physical)

Implementation Method 4

taping to erect the CNTs vertically

Methodology Applied
Scientific EffectMechanical erection: Mechanical Force

Data Source

PatentUS8513870B2Electron emission source, electric device using the same, and method of manufacturing the electron emission source
Publication Date: 2013.08.20 KOREA UNIV IND & ACADEMIC CALLABORATION FOUND
  • US8513870B2 patent drawing
  • US8513870B2 patent drawing
  • US8513870B2 patent drawing

AI summary

Provided are an electron emission source, a display apparatus using the same, an electronic device, and a method of manufacturing the display apparatus. The electron emission source includes a substrate, a cathode separately manufactured from the substrate, and a needle-shaped electron emission material layer, e.g., carbon nanotube (CNT) layer, fixed to the cathode by an adhesive layer. The CNT layer is formed by a suspension filtering method, and electron emission density is increased by a subsequent taping process on the electron emission material layer.