CNT Needle Field Emitter Manufacturing via Voltage Snapping

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Solution Overview

Problem

Existing methods for manufacturing field emission electron sources using carbon nanotubes lack controllability and simplicity, and struggle with achieving regular and efficient field emission due to uncontrolled CNT direction and mechanical challenges with small CNT sizes.

Innovation Solution

A method involving the formation of a CNT film with aligned CNTs, treating it with an organic solvent to create CNT strings, applying voltage to snap the strings into CNT needles, and securing these needles to a conductive base, enhancing controllability and conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If mechanical method is used to place single CNT on conductive base, then field emission electron source can be manufactured, but controllability is poor due to small size of single CNT

Engineering Contradiction:
ImprovecontrollabilityVSAvoidcomplexity of placing and fixing single CNT
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

Multiple individual CNTs are merged into a bundled CNT needle structure. The patent groups numerous CNTs together to form a single functional unit (CNT needle) that is placed on the conductive base as one entity, rather than attempting to place and control individual CNTs separately. This merging approach significantly improves controllability during the manufacturing process.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

Instead of directly manipulating individual CNTs, the patent uses a template or mold approach where CNTs are grown or assembled into predefined needle structures. The CNT needles are formed as copies of a desired geometry through controlled growth processes, making placement and positioning much more controllable.

Inventive Principle:
Principle #26Copying

2Ease of manufacture

If in situ synthesis method is used to form CNTs on conductive base, then CNTs can be formed directly, but direction of CNTs cannot be controlled resulting in irregular field emission electron source

Engineering Contradiction:
Improvesimplicity of forming CNTs directly on conductive baseVSAvoiddirectional control of CNTs
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The manufacturing process is segmented into distinct stages: first forming aligned CNT structures in a controlled environment, then separating them into discrete needles, and finally positioning them on the conductive base. This segmentation allows directional control during CNT formation while enabling precise positioning during placement, resolving the contradiction between ease of manufacture and manufacturing precision.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

CNTs are pre-formed with controlled alignment and orientation in a preliminary stage before being transferred to the conductive base. The CNT needles are prepared in advance with their desired directional properties already established, so that when they are placed on the conductive base, the directional control is already achieved without requiring complex in-situ manipulation.

Inventive Principle:
Principle #10Preliminary action

3Reliability

If CNT film is treated with organic solvent to form CNT strings, then CNT string structure is improved with better electric and thermal conductivity, but additional processing step is required

Engineering Contradiction:
Improveelectric and thermal conductivityVSAvoidnumber of processing steps
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The organic solvent treatment changes the physical and chemical parameters of the CNT film, including inter-tube spacing, packing density, and electrical/thermal conductivity. By controlling parameters such as solvent type, treatment time, and temperature, the CNT strings achieve optimized conductivity properties. This parameter control makes the additional processing step worthwhile for achieving reliable electrical performance.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method improves the controllability, electric and thermal conductivity, and mechanical strength of the field emission electron source, resulting in enhanced field emission efficiency and a more reliable manufacturing process.

Implementation Method 1

applying voltage between two opposite ends of the CNT string until the CNT string snaps

Methodology Applied
Scientific EffectElectrostatic force: Electrostatics

Data Source

PatentUS7914358B2Method for manufacturing field emission electron source having carbon nanotubes
Publication Date: 2011.03.29 TSINGHUA UNIVERSITY
  • US7914358B2 patent drawing
  • US7914358B2 patent drawing
  • US7914358B2 patent drawing

AI summary

A method for manufacturing a field emission electron source includes: (a) Providing a carbon nanotube (CNT) film, the CNT film has a plurality of CNTs, the CNTs are aligned along a same direction; a first electrode and a second electrode. (b) Fixing the two opposite sides of the CNT film on the first electrode and the second electrode, the CNTs in the CNT film extending from the first electrode to the second electrode. (c) Treating the CNT film with an organic solvent to form at least one CNT string. (d) Applying a voltage between two opposite ends of the CNT string until the CNT string snaps, thereby at least one CNT needle, the CNT needle has an end portion and a broken end portion. (e) Securing the CNT needle to a conductive base by attaching the end portion of the CNT needle to the conductive base.