CNT Conductive Composition With Soluble Polymer Path Formation
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Solution Overview
Problem
Existing conductive materials using carbon nanotubes and conductive polymers do not achieve sufficient conductivity and thermal conductivity due to limited conductive path formation between carbon nanotubes and solvent dispersion type conductive polymers.
Innovation Solution
A conductive composition comprising carbon nanotubes and a soluble conductive polymer, where the polymer is either doped with a sulfonic acid compound with hydrophobicity or has a sulfonic acid group-containing side chain, forming a complex that adheres to the carbon nanotubes, increasing conductive paths and enhancing conductivity and thermal conductivity.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Ease of manufacture
If solvent dispersion type conductive polymer is used with carbon nanotube, then the material can be processed easily, but the conductivity and thermal conductivity are insufficient due to limited conductive path formation
Solution Approach 1:
The patent changes the chemical structure parameters of the conductive polymer by introducing sulfonic acid groups and hydrophobic groups, transforming it from a solvent dispersion type to a soluble type. This parameter change enables the polymer to dissolve in organic solvents and form uniform coatings, while the sulfonic acid groups ensure adequate adhesion to carbon nanotubes, resolving the contradiction between processability and conductivity
Solution Approach 2:
The patent creates a composite material system combining carbon nanotubes with soluble conductive polymer (featuring sulfonic acid groups and hydrophobic groups). The carbon nanotubes provide the conductive framework, while the soluble conductive polymer fills the spaces between them and forms additional conductive paths along the nanotube surfaces, creating a synergistic composite that achieves both high conductivity and thermal conductivity while maintaining ease of processing
2Reliability
If conductive polymer is added to carbon nanotube composition, then conductivity should improve, but the conductive paths are still limited to contact points only
Solution Approach 1:
The soluble conductive polymer acts as an intermediary substance that fills the gaps between carbon nanotubes and adheres to their surfaces. The sulfonic acid groups in the polymer mediate the interaction with carbon nanotubes through adhesion, while the hydrophobic groups and solvent solubility enable the polymer to distribute uniformly and form continuous conductive paths along the nanotube circumferences, extending conductivity beyond mere contact points
Solution Approach 2:
The patent transitions the conductive path formation from a zero-dimensional contact point model to a one-dimensional linear path model along the carbon nanotube surfaces. The soluble conductive polymer enables conductive paths to extend along the circumference of carbon nanotubes, adding a dimensional aspect to conductivity that significantly increases the number and length of conductive pathways
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The composition achieves improved conductivity and thermal conductivity by forming conductive paths not only at contact points but also along the circumference of carbon nanotubes, reducing resistance and enhancing overall material performance.
Implementation Method 1
the polymer is either doped with a sulfonic acid compound with hydrophobicity or has a sulfonic acid group-containing side chain, forming a complex that adheres to the carbon nanotubes
Implementation Method 2
it has excellent conductivity or thermal conductivity, due to the electric conductivity or thermal conductivity via contact points of the carbon nanotubes
Implementation Method 3
it has excellent conductivity or thermal conductivity, due to the electric conductivity or thermal conductivity via contact points of the carbon nanotubes
Data Source
Figure 1~4

AI summary
A conductive composition including (a) a carbon nanotube, (b) a soluble conductive polymer, and (c) a solvent, wherein the soluble conductive polymer is (i) or (ii) below. (i) a complex in which a conductive polymer is doped with a sulfonic acid compound with hydrophobicity (ii) a conductive polymer having a sulfonic acid group-containing side chain