CNT-VOx Microbolometer Sensitivity Enhancement

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current microbolometer technologies face limitations in sensitivity, particularly at smaller pixel sizes and in the 20 mK noise equivalent delta temperature (NEDT) range, due to 1/f noise and the inherent properties of vanadium oxide and silicon materials, which restrict their performance in thermal infrared detection.

Innovation Solution

The development of microbolometer structures using carbon nanotube-silicon vanadium oxide or amorphous silicon nanocomposites, where carbon nanotubes are deposited on a CMOS wafer with readout circuitry, creating a thin film that increases the temperature coefficient of resistance (TCR) and reduces noise floor, enabling sensitivity enhancement to less than 1 mK.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional microbolometer structures using vanadium oxide or amorphous silicon are used, then the device can detect infrared radiation, but the sensitivity is limited to NEDT values around 20 mK due to 1/f noise and material properties

Engineering Contradiction:
ImprovesensitivityVSAvoidnoise floor
Core Design Contradiction:
Measurement precisionVSObject-affected harmful factors

Solution Approach 1:

The patent employs a composite structure combining carbon nanotubes with vanadium oxide or amorphous silicon materials. The carbon nanotubes are integrated into the microbolometer's absorbing layer, creating a nanocomposite material that leverages the high thermal conductivity and electrical properties of CNTs alongside the infrared-absorbing characteristics of VOx or a-Si, thereby reducing noise and enhancing sensitivity

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention modifies key physical parameters of the detector by incorporating carbon nanotubes, which change the temperature coefficient of resistance (TCR) and thermal conductivity of the absorbing layer. These parameter changes enable the detector to achieve superior sensitivity with NEDT values below 10 mK by optimizing the thermal and electrical response characteristics

Inventive Principle:
Principle #35Parameter changes

2Productivity

If pixel size is reduced to increase detector array density, then more detection elements can be packed, but sensitivity deteriorates due to increased 1/f noise and realization of absolute noise floor

Engineering Contradiction:
Improvedetector array densityVSAvoidsensitivity
Core Design Contradiction:
ProductivityVSMeasurement precision

Solution Approach 1:

By incorporating carbon nanotubes into the microbolometer structure, the patent changes the fundamental noise characteristics and temperature coefficient of resistance parameters. This allows smaller pixel sizes to maintain high sensitivity because the CNT-enhanced materials provide superior signal-to-noise ratios even at reduced dimensions

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The carbon nanotube-composite materials enable high-density pixel arrays by providing enhanced thermal and electrical properties that compensate for the reduced pixel area. The nanocomposite structure maintains adequate thermal isolation and electrical response even when pixels are closely packed

Inventive Principle:
Principle #40Composite materials

3Measurement precision

If carbon nanotube-silicon vanadium oxide or amorphous silicon nanocomposites are used, then sensitivity increases to below 10 mK NEDT, but device complexity increases due to additional nanocomposite fabrication steps

Engineering Contradiction:
ImprovesensitivityVSAvoidfabrication process complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The carbon nanotube nanocomposite layer serves multiple functions simultaneously: it enhances the temperature coefficient of resistance, improves thermal conductivity, reduces noise floor, and maintains infrared absorption. This multi-functionality justifies the additional fabrication complexity by delivering superior detector performance across multiple parameters

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent utilizes the porous or network structure of carbon nanotube films to create a high-surface-area composite material that can be deposited as a thin layer. This porous structure allows for efficient infrared absorption and thermal management while maintaining compatibility with existing microbolometer fabrication processes

Inventive Principle:
Principle #31Porous materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in highly sensitive infrared detectors capable of achieving NEDT values below 10 mK, surpassing previous limitations, with improved thermal conductivity and noise reduction, while maintaining compatibility with CMOS processing for cost-effectiveness.

Implementation Method 1

the thin film of bundled carbon nanotubes is tuned to be sensitive to IR radiation in the micron band of 1 to 12 microns and the exposure of IR radiation induces a change in impedance

Methodology Applied
Scientific EffectAbsorption (EM radiation): Absorption (EM radiation)

Implementation Method 2

a thin film that increases the temperature coefficient of resistance (TCR) and reduces noise floor

Methodology Applied
Scientific EffectTemperature coefficient of resistance: Thermo-resistive Effect

Data Source

PatentUS9677946B1Infrared radiation detectors using carbon nanotubes-silicon vanadium oxide and or amorphous silicon nanoparticles-CNT nanocomposites and methods of constructing the same
Publication Date: 2017.06.13 MAGNOLIA OPTICAL TECH
  • US9677946B1 patent drawing
  • US9677946B1 patent drawing
  • US9677946B1 patent drawing

AI summary

The present disclosure relates to microbolometer structures having top layers of amorphous silicon or vanadium oxide. In some examples, combinations of carbon nanotubes, nanoparticles, and/or thin films can be deposited atop the existing top layer of amorphous silicon or top layer of vanadium oxide of a microbolometer structure. Such configurations can increase the sensitivity of the microbolometers to less than 4 mK, less than 2 mK, and in some examples less than 1 mK.