CO Isotope Rectification With Heat Pump Reboiling

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current systems for separating CO isotopes, such as 13C16O from natural CO, require high power consumption due to the need for liquid nitrogen cooling, which increases energy costs and operational inefficiencies.

Innovation Solution

Implementing a heat pump cycle as a heating means in the rectification column system, which uses nitrogen as a working fluid to provide both heating and cooling capacities, reducing the reliance on external cooling sources and minimizing energy requirements.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If liquid nitrogen cooling is used in the rectification column system, then the separation of CO isotopes is achieved, but the power consumption increases significantly

Engineering Contradiction:
Improveseparation efficiencyVSAvoidpower consumption
Core Design Contradiction:
Manufacturing precisionVSUse of energy by moving object

Solution Approach 1:

The patent combines the cooling function (liquid nitrogen condenser) and heating function (electric heater) into a single heat pump system. The heat pump uses nitrogen as working fluid to provide both cooling at the top of the rectification column and heating at the bottom, eliminating the need for separate liquid nitrogen supply and reducing overall energy consumption while maintaining separation efficiency.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The heat pump system performs multiple functions simultaneously: it acts as both a condenser (cooling device) at the top of the column and a reboiler (heating device) at the bottom. This multi-functionality reduces the number of separate components needed and optimizes energy utilization by recovering heat from the condensation process to assist in the evaporation process.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Stability of the object's composition

If electric heaters are used in each rectification section, then evaporation is maintained, but energy costs increase

Engineering Contradiction:
Improveevaporation maintenanceVSAvoidenergy cost
Core Design Contradiction:
Stability of the object's compositionVSUse of energy by stationary object

Solution Approach 1:

The patent changes the energy supply parameters by replacing direct electric heating with heat pump-based heating. The heat pump delivers heat at the required temperature levels using compressed nitrogen, optimizing the energy input-output relationship and reducing overall energy costs while maintaining stable evaporation conditions in each rectification section.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If multiple rectification sections are arranged in chain-like manner, then separation precision is improved, but system complexity increases

Engineering Contradiction:
Improveseparation precisionVSAvoidsystem complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent merges the cooling and heating systems into a single integrated heat pump unit that serves all rectification sections. This integration reduces the number of independent components and connections needed, simplifying the overall system architecture while preserving the multi-section chain-like arrangement required for high separation precision.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The heat pump cycle effectively reduces energy consumption by providing at least 50% of the heating needs, allowing for more efficient separation of CO isotopes with reduced operational costs and increased system reliability.

Implementation Method 1

the heating in least one of the plurality of rectification sections is provided by heating means comprising a heat pump cycle

Methodology Applied
Scientific EffectHeat pump cycle: Heat Exchanger

Implementation Method 2

maintaining evaporation of liquid present in the rectification column is achieved by heating the liquid by heating means provided in each rectification section

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS11617986B2Method and apparatus for separation of 13C16O from natural CO
Publication Date: 2023.04.04 LINDE AG
  • US11617986B2 patent drawing
  • US11617986B2 patent drawing
  • US11617986B2 patent drawing

AI summary

Method and Apparatus for separating at least one CO isotope compound, especially isotope compound 13C16O, from natural CO, comprising:a rectification column system (110) comprising a plurality of rectification sections (112,114,116,118,120) arranged adjacent to one another in a chain-like manner, including an upper rectification section (112) and a plurality of lower rectification sections (114,116,118,120), each rectification section comprising a heating means (112a,114a,116a,118a,120a) to maintain evaporation of liquid present therein, provided that the heating means (112a) of the at least one of the plurality of rectification sections (112) is provided to comprise a heat pump cycle (112b).