Co-Ni Atomic Layer Magnetic Material for Low-Temperature Anisotropy

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Solution Overview

Problem

The manufacturing of hard magnetic materials is hindered by the need for high substrate and heat treatment temperatures, chemical inertness of noble metals, and high costs and scarcity of rare-earth metals, which complicates processing and material stability.

Innovation Solution

A magnetic material with a structure of alternately stacked Co and Ni layers, formed at room temperature using deposition methods, exhibiting six-fold symmetry and high reactivity, allowing for easy patterning and cost-effective production.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If high substrate temperature and high heat treatment temperature are used to achieve high perpendicular magnetic anisotropy in hard magnetic materials, then magnetic anisotropy is improved, but manufacturing complexity and cost increase due to temperature constraints on other devices and substrate

Engineering Contradiction:
Improveperpendicular magnetic anisotropyVSAvoidmanufacturing process complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent uses a composite layered structure of Co and Ni atomic layers, where the combination of these two materials produces perpendicular magnetic anisotropy at lower temperatures than conventional hard magnetic materials. The interface between Co and Ni layers creates the necessary magnetic anisotropy without requiring high heat treatment temperatures.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the fundamental parameters of the magnetic material system by using alternating Co and Ni atomic layers with specific thicknesses (Co: 0.3-0.6 nm, Ni: 0.3-0.6 nm). This parameter change enables the material to achieve high perpendicular magnetic anisotropy at substrate temperatures of 300°C or lower, avoiding the high temperature requirements of conventional materials.

Inventive Principle:
Principle #35Parameter changes

2Strength

If noble metals like Pt, Pd, or Au are used to achieve high magnetic anisotropy, then magnetic performance is improved, but chemical reactivity decreases making reactive ion etching difficult

Engineering Contradiction:
Improvemagnetic anisotropyVSAvoidreactive ion etching ease
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The patent replaces expensive noble metals (Pt, Pd, Au) with more reactive and abundant transition metals (Co and Ni). These materials are etched more easily by reactive ion etching and can be processed at lower costs, while still achieving the required magnetic anisotropy through their layered atomic structure.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent changes the material composition from noble metals to transition metals (Co and Ni), which have different chemical reactivity properties. This parameter change enables effective reactive ion etching while maintaining high magnetic anisotropy through the specific atomic layer structure and six-fold symmetry arrangement.

Inventive Principle:
Principle #35Parameter changes

3Strength

If rare-earth metals like Nd, Dy, Sm, Tb, or Gd are used to achieve high magnetic anisotropy, then magnetic performance is improved, but raw material cost increases and supply becomes uncertain

Engineering Contradiction:
Improvemagnetic anisotropyVSAvoidraw material availability
Core Design Contradiction:
StrengthVSQuantity of substance

Solution Approach 1:

The patent replaces scarce and expensive rare-earth metals with abundant transition metals (Co and Ni). These materials are readily available, cost-effective, and can be processed using standard semiconductor manufacturing techniques, eliminating supply chain concerns associated with rare-earth metals.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent creates a composite structure using Co and Ni atomic layers that collectively provide the necessary magnetic anisotropy without requiring rare-earth elements. The synergistic interaction at the Co-Ni interfaces generates the required magnetic properties from abundant materials.

Inventive Principle:
Principle #40Composite materials

4Stability of the object's composition

If conventional hard magnetic materials are used to hold information stably, then information storage stability is improved, but processing by reactive ion etching becomes difficult due to low chemical reactivity

Engineering Contradiction:
Improveinformation storage stabilityVSAvoidreactive ion etching ease
Core Design Contradiction:
Stability of the object's compositionVSEase of manufacture

Solution Approach 1:

The patent changes the material composition from conventional hard magnetic materials with low reactivity to Co-Ni layered structures with higher chemical reactivity. This enables effective reactive ion etching for patterning while the perpendicular magnetic anisotropy in the layered structure ensures stable information storage through high magnetic anisotropy energy.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Facilitates the production of hard magnetic materials with high magnetic anisotropy at lower temperatures, maintains material characteristics, and reduces raw material costs by using abundant transition metals like Co and Ni.

Implementation Method 1

formed by deposition with one of a sputtering method, a vacuum deposition method, a molecular beam epitaxy method, a laser ablation method, and an ion plating method

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Data Source

PatentUS10706996B2Magnetic material and method of manufacturing the same
Publication Date: 2020.07.07 TOHOKU UNIV
  • US10706996B2 patent drawing
  • US10706996B2 patent drawing
  • US10706996B2 patent drawing

AI summary

A magnetic material includes a structure in which a first magnetic layer 1 and a second magnetic layer 2 are stacked such that each layer is formed at least partially in a stacking direction by substantially one atomic layer. The first magnetic layer contains Co as a principal component. The second magnetic layer includes at least Ni. The magnetic material has magnetic anisotropy in the stacking direction. Preferably, an atomic arrangement within a film surface of the first magnetic layer and the second magnetic layer has six-fold symmetry.