CO Shift Catalyst Temperature Control via Dynamic Gas Flow

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Solution Overview

Problem

The CO shift reaction apparatus faces challenges in maintaining the CO shift catalyst within a predetermined temperature range due to variations in gas flow rate and composition, leading to catalyst deterioration and inefficient gas refinement.

Innovation Solution

The apparatus includes multiple reactors with varying CO shift catalyst layer lengths and gas flow rate control units to adjust gas supply and separation, ensuring the catalyst operates within the optimal temperature range despite variations in gas flow and composition.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the CO shift reaction is allowed to proceed while the CO shift catalyst is in the predetermined temperature range, then the CO shift reaction efficiency is improved, but the device complexity increases due to the need for multiple reactors and coolers

Engineering Contradiction:
ImproveCO shift reaction efficiencyVSAvoidnumber of reactors and coolers
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent makes the gas supply amount adjustable and dynamic through gas flow rate control units. The gas supply to each reactor can be flexibly changed based on gas flow rate and composition variations, allowing the system to maintain catalyst temperature within the optimal range without requiring multiple reactors and coolers. This dynamic adjustment capability resolves the contradiction by achieving efficient CO shift reaction while simplifying the device structure.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent changes the parameter of gas supply amount to control the reaction conditions. By adjusting the gas flow rate and composition parameters, the system can maintain the catalyst temperature within the predetermined range while optimizing the CO shift reaction efficiency. This parameter change approach allows single-reactor operation to achieve the same effect as multiple reactors, thereby reducing device complexity.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If the cooler size is determined based on the original design gas flow rate, then the manufacturing cost is controlled, but the reliability decreases when gas flow rate and composition vary significantly from design conditions

Engineering Contradiction:
Improvecooler manufacturingVSAvoidcatalyst temperature control
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent introduces feedback control through gas flow rate control units that monitor and adjust the gas supply amount based on actual gas flow rate and composition. This feedback mechanism ensures the catalyst temperature remains within the optimal range even when operating conditions deviate from the original design, thereby maintaining high reliability without requiring an oversized cooler.

Inventive Principle:
Principle #23Feedback

3Duration of action of stationary object

If multiple reactors and coolers are used to maintain catalyst temperature, then the catalyst lifespan is extended, but the device complexity and manufacturing cost increase

Engineering Contradiction:
Improvecatalyst lifespanVSAvoidnumber of reactors and coolers
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

By making the gas supply amount dynamically adjustable through gas flow rate control units, the system can maintain catalyst temperature within the optimal range for extended periods, thereby extending catalyst lifespan. This dynamic control approach achieves the same protective effect as multiple reactors and coolers but with simpler and less expensive equipment.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration efficiently produces reformed gas while extending the lifespan of the CO shift catalyst, allowing for stable and flexible operation of the gas refining process.

Implementation Method 1

a CO shift reaction in which carbon monoxide (CO) reacts with water to produce hydrogen (H2) and carbon dioxide (CO2) is applied

Methodology Applied
Scientific EffectCO shift reaction: Chemical Bonding

Implementation Method 2

a CO shift catalyst which accelerates the reaction in which CO contained in the gasification gas is reformed and converted into CO2

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 3

since the CO shift reaction is an exothermic reaction, the gasification gas is heated by the CO shift reaction in the CO shift reaction apparatus and thus the CO shift catalyst is heated

Methodology Applied
Scientific EffectExothermic reaction: Exothermic Reaction

Data Source

PatentUS9238208B2CO shift reaction apparatus and gasification gas refining system
Publication Date: 2016.01.19 MITSUBISHI HEAVY IND LTD
  • US9238208B2 patent drawing
  • US9238208B2 patent drawing
  • US9238208B2 patent drawing

AI summary

A CO shift reaction apparatus 11 according to the present invention includes: adiabatic reactors 31A to 31C, each having CO shift catalyst layers 35A to 35C filled with a CO shift catalyst 34 which reforms CO in gasification gas 15; gas supply lines l11 to l15 which supply the gasification gas 15 to the adiabatic reactors 31A to 31C; first gas flow rate control units 32A and 32B which adjust the amounts of gas supplied to the adiabatic reactors 31A to 31C; gas discharge lines l21 to l25 which discharge processing gas; and second gas flow rate control unit 33A and 33B which adjust flow rates of processing gas 38A-1, 38A-2, 38B-1, and 38B-2.