CO2-Based Battery Cell Monitoring for Parallel Aging Imbalance

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Solution Overview

Problem

Detecting imbalanced aging among parallel-connected battery cells in electric vehicles is challenging due to identical cell voltages, which can lead to cathode overpotential and inefficiencies in power density.

Innovation Solution

A battery monitoring system that measures carbon dioxide concentrations within each cell to detect cathode overpotential by correlating CO2 generation with overcharging, using sensors and a controller to adjust charging or discharging parameters based on CO2 differences.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If battery cells are connected in parallel to increase power density, then power output is improved, but detecting imbalanced aging becomes difficult due to identical cell voltages

Engineering Contradiction:
Improvepower densityVSAvoidimbalanced aging detection
Core Design Contradiction:
PowerVSDifficulty of detecting and measuring

Solution Approach 1:

The patent uses carbon dioxide concentration as an intermediary parameter to detect cathode overpotential. Since parallel-connected cells have identical voltages making direct comparison ineffective, the system measures CO2 concentration in the electrolyte as a mediator that reflects the actual chemical state and aging level of each cell, enabling indirect detection of imbalances that voltage alone cannot reveal

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces traditional voltage-based electrical measurement with a chemical measurement approach. Instead of relying on electrical parameters (voltage, current) that are identical in parallel connections, the system substitutes with chemical sensing of CO2 concentration, which provides unique information about each cell's electrochemical state and aging condition

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Productivity

If charging parameters are increased to improve power density, then charging speed is improved, but cathode overpotential occurs leading to imbalanced aging

Engineering Contradiction:
Improvecharging speedVSAvoidcell balance
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent implements a feedback control system where CO2 concentration measurements from each cell are continuously monitored and fed back to the charging control system. When a cell exhibits elevated CO2 levels indicating approaching overpotential, the system automatically adjusts charging parameters to prevent imbalanced aging, enabling high charging speeds while maintaining cell balance through real-time adaptive control

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent performs preliminary detection of cathode overpotential conditions by monitoring CO2 concentration trends before actual overcharging occurs. By detecting early signs of imbalance through CO2 measurements, the system can proactively adjust charging parameters to prevent overpotential development, rather than reacting after damage has occurred

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Effectively identifies and mitigates cathode overpotential by adjusting charging parameters, thereby maintaining optimal battery performance and increasing power density.

Implementation Method 1

measuring a carbon dioxide concentration within the battery cell; detecting a cathode overpotential in the battery cell in response to the measured carbon dioxide concentration

Methodology Applied
Scientific EffectCarbon dioxide generation through electrochemical reactions: Electrolysis

Data Source

PatentUS12463265B2Battery monitoring system for measuring carbon dioxide to detect imbalance in a group of parallel lithium-ion battery cells
Publication Date: 2025.11.04 GM GLOBAL TECHNOLOGY OPERATIONS LLC
  • US12463265B2 patent drawing
  • US12463265B2 patent drawing
  • US12463265B2 patent drawing

AI summary

A battery monitoring system includes a carbon dioxide sensing system configured to selectively measure carbon dioxide concentrations within a plurality of battery cells, respectively, that are connected in parallel. A controller is configured to detect cathode overpotential in the plurality of battery cells in response to the measured carbon dioxide concentrations of the plurality of battery cells.