CO2 Electrolyzer System for Renewable Fuel and Chemical Production

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Solution Overview

Problem

Current systems lack the capability to efficiently produce both renewable fuels and chemicals on a large scale, as existing technologies are either too costly or not economically viable for widespread adoption, and there is a need for a system that can easily switch between fuel and chemical production to take advantage of growing markets.

Innovation Solution

A production system comprising a CO2 electrolyzer, a water electrolyzer, a mix point to combine outputs, a control unit to adjust CO2 to H2 ratios, and a series of reactors for converting CO and H2 into fuels or chemicals, utilizing an anion-conducting polymeric membrane and zeolite catalysts, allowing for easy switching between fuel and chemical production.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If large-scale production facilities are built to reduce costs through economies of scale, then production costs decrease, but the investment required becomes prohibitively high for small markets

Engineering Contradiction:
Improveproduction costVSAvoidinvestment scale
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

The electrolyzer system is designed to perform multiple functions by producing different product ratios. By adjusting the CO2 to H2 ratio in the syngas stream, the same facility can produce either renewable fuels (higher H2 content) or renewable chemicals (higher CO content), allowing one plant to serve multiple markets and justify larger scale investment

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The system incorporates dynamic control capabilities where the product mix can be adjusted in real-time based on market conditions. The electrolyzer operation parameters (current density, gas flow rates, pressure) can be dynamically modified to shift between fuel and chemical production modes, providing operational flexibility at scale

Inventive Principle:
Principle #15Dynamics

2Productivity

If the system is designed to produce renewable fuels to meet large market demands, then fuel production capacity increases, but the ability to produce renewable chemicals decreases

Engineering Contradiction:
Improvefuel production capacityVSAvoidproduct switching capability
Core Design Contradiction:
ProductivityVSAdaptability or versatility

Solution Approach 1:

The electrolyzer system is designed to perform multiple functions by producing different product ratios. By adjusting the CO2 to H2 ratio in the syngas stream, the same facility can produce either renewable fuels (higher H2 content) or renewable chemicals (higher CO content), allowing one plant to serve multiple markets

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The system changes operational parameters (CO2 feed rate, H2O electrolysis rate, syngas composition) to switch between product types. By controlling the ratio of CO to H2 in the product stream, the system can optimize for either fuel synthesis (requiring specific C:H ratios) or chemical production (requiring different compositions)

Inventive Principle:
Principle #35Parameter changes

3Productivity

If existing technologies are used for renewable fuel production, then current market demands can be met, but production costs remain too high for economic viability

Engineering Contradiction:
Improverenewable fuel outputVSAvoidproduction cost
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The system recovers and utilizes CO2 that would otherwise be a waste product or require expensive capture. By electrolyzing CO2 directly to produce syngas components (CO and H2), the system turns a greenhouse gas into a valuable feedstock, reducing raw material costs and potentially generating carbon credits

Inventive Principle:
Principle #34Discarding and recovering

Solution Approach 2:

The system replaces traditional thermal conversion processes (gasification, reforming) with electrochemical conversion. This substitution enables operation at lower temperatures, reducing energy input requirements and allowing for more efficient heat management, thereby lowering overall production costs

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the production of synthetic fuels and chemicals at reduced costs by leveraging economies of scale, achieving high selectivity and efficiency in converting CO2 and H2 into valuable products like gasoline, diesel, and olefins, while being carbon negative and energy-efficient.

Implementation Method 1

uses a CO2 electrolyzer with a special membrane that enables CO2 electrolysis to be accomplished at temperatures up to 120° C

Methodology Applied
Scientific EffectIon conduction: Conduction (electrical)

Implementation Method 2

converting CO2 to CO via a CO2 electrolyzer

Methodology Applied
Scientific EffectElectrolysis: Electrolysis

Implementation Method 3

converting H2O to H2 via a water electrolyzer

Methodology Applied
Scientific EffectElectrolysis: Electrolysis

Implementation Method 4

a series of reactors for converting CO and H2 into fuels or chemicals, utilizing an anion-conducting polymeric membrane and zeolite catalysts

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentUS10280378B2System and process for the production of renewable fuels and chemicals
Publication Date: 2019.05.07 DIOXIDE MATERIALS INC
  • US10280378B2 patent drawing
  • US10280378B2 patent drawing
  • US10280378B2 patent drawing

AI summary

A renewable fuel production system includes a carbon dioxide capture unit for extracting carbon dioxide from atmospheric air, a carbon dioxide electrolyzer for converting carbon dioxide to carbon monoxide, a water electrolyzer for converting water to hydrogen, a synfuels generator for converting carbon monoxide produced by the carbon dioxide electrolyzer and hydrogen produced by the water electrolyzer to a fuel. The fuel produced can be synthetic gasoline and/or synthetic diesel. A renewable fuel production process includes the steps of extracting carbon dioxide from atmospheric air via a carbon dioxide capture unit, converting carbon dioxide to carbon monoxide via a carbon dioxide electrolyzer, converting water to hydrogen via a water electrolyzer, and converting carbon monoxide produced via the carbon dioxide electrolyzer and H2 produced via the water electrolyzer to a fuel. The system is also capable of simultaneously or alternatively producing a separate industrial chemical.