CO2-Enriched Water for Gypsum Slurry Fluidity

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Solution Overview

Problem

The existing methods for preparing stucco slurries require excessive water, leading to high energy costs for drying, as more water than stoichiometrically necessary is used to achieve fluidity and low viscosity, which is then removed, resulting in significant energy expenditure.

Innovation Solution

Introducing a measured quantity of carbon dioxide into the process water before mixing with stucco increases slurry fluidity, allowing for a reduction in overall water usage and potentially reducing the amount of foaming agents needed, while using gaseous carbon dioxide avoids by-products from acid-base reactions and leverages abundant, low-cost CO2 from fossil fuel heating systems.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If more water is used to achieve fluidity and low viscosity of stucco slurry, then processing properties are improved, but energy consumption for drying increases significantly

Engineering Contradiction:
Improvefluidity and low viscosityVSAvoidenergy consumption for drying
Core Design Contradiction:
Ease of operationVSUse of energy by moving object

Solution Approach 1:

The patent introduces carbon dioxide into the process water to change the chemical parameters of the water, specifically lowering its pH. This parameter change allows the stucco slurry to achieve adequate fluidity and low viscosity with reduced water content, thereby resolving the contradiction between processing properties and drying energy consumption

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

Carbon dioxide acts as an intermediary substance that modifies the properties of process water. By dissolving CO2 into the water, the patent creates carbonic acid which reduces pH and enhances the fluidity of the stucco slurry, allowing reduced water usage while maintaining processing quality

Inventive Principle:
Principle #24Intermediary (Mediator)

2Quantity of substance

If stoichiometric amount of water is used for hemihydrate hydration, then water demand is reduced, but fluidity and processability of mixture deteriorate

Engineering Contradiction:
Improvewater demandVSAvoidfluidity and processability
Core Design Contradiction:
Quantity of substanceVSEase of operation

Solution Approach 1:

The patent changes the chemical parameter (pH) of the process water by introducing carbon dioxide. This parameter change enables the slurry to maintain adequate fluidity and processability with water amounts closer to the stoichiometric requirement, thus reducing overall water demand while preserving workability

Inventive Principle:
Principle #35Parameter changes

3Duration of action of moving object

If CO2 is introduced into slurry after mixing stucco and water, then setting time is increased and durability is improved, but water demand increases

Engineering Contradiction:
Improvesetting timeVSAvoidwater demand
Core Design Contradiction:
Duration of action of moving objectVSQuantity of substance

Solution Approach 1:

The patent applies preliminary action by introducing carbon dioxide into the process water before mixing with stucco. This pre-treatment of the water modifies its properties in advance, allowing reduced water demand in the final slurry while still achieving adequate setting time and durability through the chemical modification already present in the water

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method reduces the water demand for stucco slurries, achieving energy savings and minimizing the use of foaming agents, with optimal CO2 concentrations between 1-8 g/L ensuring adequate processing properties and efficient drying.

Implementation Method 1

introducing a measured quantity of carbon dioxide into the process water prior to mixing the process water with the stucco

Methodology Applied
Scientific EffectDissolution: Solvation

Implementation Method 2

The addition of CO2 to the slurry allows for larger quantities of water... The increased amount of water is described as favourable because it reduces the risk of spoiling

Methodology Applied
Scientific EffectAcid-base reaction: Chemical Bonding

Data Source

PatentUS20220017420A1Use of CO2 as Water Demand Reducer in Gypsum Stucco Rehydration Mortars
Publication Date: 2022.01.20 KNAUF GIPS KG
  • US20220017420A1 patent drawing

AI summary

The present application concerns a method for the production of a gypsum article, which includes introducing a measured quantity of carbon dioxide into the process water and mixing the stucco with the thus treated water. The CO2-enriched water has the advantage of providing compositions with sufficient processing properties at considerably lower water contents, thus allowing for significant energy savings. The invention also concerns slurries prepared according to this method as well as an apparatus which is adapted to implement this method.